The Phenylenes

亚苯基

• 批准号: 9202152
• 负责人: K. Peter Vollhardt
• 金额: $ 56.9万
• 依托单位: University of California-Berkeley
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1992
• 资助国家: 美国
• 起止时间: 1992-05-01 至 1997-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9202152&HistoricalAwards=false
• 关键词: Phenylenes

The focus of this research is the development of synthetic methods for the preparation of novel aromatic compounds composed of alternating fused benzene and cyclobutadiene rings. Related structures include extended sp-carbon nets and heterocyclic analogs. The compounds may show superconducting behavior and their unique topology makes them viable precursors to novel hydrocarbon cages and related assemblies. Access to the compounds will be afforded via transition metal catalysis. %%% With this award, the Synthetic Organic Program is supporting the research of Dr. K. Peter C. Vollhardt of the Department of Chemistry at the University of California, Berkeley. Professor Vollhardt will focus his work on the synthesis a new class of aromatic compounds known as the phenylenes. These compounds have interesting theoretical implications, could exhibit superconductive behavior and will serve as precursors to novel hydrocarbon cage assemblies.

本研究的重点是开发合成的 制备新型芳族化合物的方法 由交替稠合的苯环和环丁二烯环组成。 相关结构包括扩展的sp-碳网和 杂环类似物。 这些化合物可能表现出超导性 行为和它们独特的拓扑结构使它们成为可行的前体 涉及新型烃笼和相关组件。 获得 该化合物将通过过渡金属催化得到。 %%% 有了这个奖项，合成有机计划正在支持 K博士的研究Peter C.福尔哈特 化学在加州大学伯克利分校。 教授 Vollhardt将把他的工作重点放在合成一类新的 被称为亚苯基的芳香族化合物。 这些化合物 具有有趣的理论意义，可以展示 行为，并将作为先驱，以新的 烃笼组件。