Synthesis of Novel Microporous Solids Containing Vanadium

本研究的目的是合成新的有机- 无机层状结构，其具有特定的吸附位点 有机分子，并研究新的扩展的合成 基于VO 5正方形金字塔连接框架的网格， 四面体含氧阴离子。 随后除去客体物质 从固体中产生的化合物可以表现出高度的选择性， 在随后的反应中的分子吸附和离子络合。 新相将以粉末和单晶为特征 衍射方法，磁化率测量和 吸附等温线和动力学的测定。 这些研究 在催化过程中具有特殊的价值， 生产燃料和化学品。

The objectives of this research are to synthesize new organic- inorganic layered structured with adsorption sites for specific organic molecules and to investigate the synthesis of new extended lattices based on connected frameworks of VO5 square pyramids with tetrahedral oxyanions. Subsequent removal of the guest species from the solid leads to compounds which can show highly selective molecular sorption and ion complexation in subsequent reactions. The new phases will be characterized by powder and single crystal diffraction methods, magnetic susceptibility measurements and the determination of sorption isotherms and kinetics. These studies are of special value in catalysis for processes involving the production of fuels and chemicals.