New Chemistry of Bimetallic Fischer Carbene Complexes

9313746芬兰本研究的重点是双金属菲舍尔卡宾配合物的化学研究进展，该配合物含有一个附加的、缺电子的、连接在卡宾杂原子上的金属中心。第二金属中心用于提高络合物的反应活性，并作为卡宾和底物部分组织的模板，从而导致选择性转化。此外，还将探索用于催化卡宾转移的试剂的潜力。%有了这个续期奖，合成有机计划正在支持弗吉尼亚大学化学系的M.G.芬恩博士的研究。芬恩教授将把他的工作重点放在费歇尔络合物的化学上，这是一种卡宾络合物，它与碳-碳双键和三键进行各种反应。***

9313746 Finn The focus of this research is the development of the chemistry of bimetallic Fischer carbene complexes containing an added, electron deficient, metal center attached to the carbene heteroatom. The second metal center serves to heighten the reactivity of the complexes and acts as a template for the organization of the carbene and substrate moieties leading to selective transformations. The potential of the reagents for catalytic carbene transfer will also be explored. %%% With this renewal award, the Synthetic Organic Program is supporting the research of Dr. M.G. Finn of the Department of Chemistry at the University of Virginia. Professor Finn will focus his work on the chemistry of Fischer complexes, carbene complexes that that engage in a wide variety of reactions with carbon-carbon double and triple bonds. ***