Integration of Multinuclear NMR Spectroscopy into the Chemistry Undergraduate Curriculum

9451673朔伊尔正在北卡罗来纳大学教堂山分校化学系开发一个“跨学科”的无机合成实验室，该实验室将涵盖包括固态化学、聚合物化学、材料化学、主族化学、有机金属化学和配位化学在内的广泛课题。围绕最近的研究进展，已经努力设计了几个实验，给学生们现代无机化学的味道。该提案要求资金购买一台200兆赫傅里叶变换核磁共振光谱仪，该光谱仪将被广泛用于该实验室的反应产物的表征。这个实验室是所有化学专业的必修课(每年有80-100名学生参加)，并将作为我们的专业教授多核傅立叶变换核磁共振波谱主题的工具。为了处理我们计划中涉及的大量学生，核磁共振光谱仪将配备一个自动样品加载器、自动化软件和一个四探头，提供对1H、31P、19F和13C谱的常规访问。虽然学生对这台仪器的日常数据采集的参与将微乎其微，但学生们将密切参与在化学系30个站的个人计算机实验室处理自己的数据。我们正在建立的项目将作为将现代核磁共振光谱学引入其他具有类似大量化学专业的项目的典范。此外，同样的仪器将用于加强其他实验室的学生的教育经验，这些实验室的人数相当少，包括荣誉有机实验室、聚合物合成实验室和高级有机合成实验室。

9451673 Schauer An "interdisciplinary" inorganic synthesis laboratory is being developed in the Chemistry department at the University of North Carolina at Chapel Hill that will cover a broad range of topics including solid-state chemistry, polymer chemistry, materials chemistry, main-group chemistry, organometallic chemistry, and coordination chemistry. An effort has been made to design several experiments around recent research developments to give students the flavor of modern inorganic chemistry. This proposal requests funds to purchase a 200 MHz Fourier Transform Nuclear Magnetic Resonance spectrometer that will be utilized extensively for characterization of reaction products in this laboratory. This laboratory is a required course for all chemistry majors (taken by 80-100 students per year), and will serve as a vehicle for the education of our majors on the topic of Multinuclear FT-NMR Spectroscopy. To handle the large numbers of students involved in our program, the NMR spectrometer will be equipped with an automatic sample loader, automation software, and a quad probe that will provide routine access to 1H, 31P, l9F, and 13C spectra. Although student involvement in routine data acquisition with this instrument will be minimal, the students will be intimately involved in working-up their own data in the 30-station Chemistry Department personal computer laboratory. The program that we are establishing will serve as a model for bringing modern NMR spectroscopy into other programs with similarly large numbers of chemistry majors. Furthermore, this same instrumentation will be used to enhance the educational experiences of students in other laboratories where the numbers are reasonably small, including the honors organic laboratory, the polymer synthesis laboratory, and the advanced organic synthesis laboratory.