Photochemistry of Main Group Clusters

主族簇的光化学

• 批准号: 9521572
• 负责人: James Spencer
• 金额: $ 21.9万
• 依托单位: Syracuse University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1995
• 资助国家: 美国
• 起止时间: 1995-08-01 至 1998-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9521572&HistoricalAwards=false
• 关键词: Photochemistry; Main; Group; Clusters

Dr. James T. Spencer, Chemistry Department, Syracuse University, is supported by the Inorganic, Bioinorganic, and Organometallic Chemistry Program of the Chemistry Division for the study of the photochemistry of main-group metal cage compounds. The important photochemical pathways of borane and metallaborane clusters will be determined and the mechanisms of these processes will be investigated. This will lead both to a description of the range of phototransformations available to clusters and to a clearer picture of fundamental molecular photoprocesses which these molecules will undergo. Light induced chemical transformations are of extreme importance in several areas of chemistry. In this study the behavior of boron containing cage molecules, when irradiated with intense light, will be determined. This will lead both to the basic `photochemical` behavior of cage type molecules and to advances in the preparation of new boron containing electronic materials.

锡拉丘兹大学化学系詹姆斯·T·斯宾塞（James T.将确定硼烷和金属烷簇的重要光化学途径，并将研究这些过程的机制。这将导致对簇可用的光转化范围的描述，以及对这些分子将经历的基本分子光程序的更清晰图片。 在几个化学领域，光诱导的化学转化至关重要。在这项研究中，将确定含硼的行为，含有笼子分子时，将确定用强光照射。这将导致笼子型分子的基本“光化学”行为，以及在制备含有电子材料的新硼的过程中的进步。