课题基金 / 基金详情

Allene Directed Asymmetric Synthesis

Allene Directed Asymmetric Synthesis
丙二烯定向不对称合成
批准号:
9525974
负责人:
James Marshall
金额:
$44.87万
依托单位国家:
美国
项目类别:
Continuing Grant
财政年份:
1996
资助国家:
美国
项目状态:
已结题
起止时间:
1996-01-01 至 1999-12-31

项目摘要

项目成果

James Marshall的其他基金

相似基金

相关文献

中文摘要
翻译
这项研究的重点将是开发使用手性烯金属试剂锡、硼、钛、铬和钯的合成方法。将特别注意醛的亲电取代加成反应,以此作为合成对映体富含丙叉醇和烯丙醇的一种途径。甲醇的精制将允许合成具有重要生物学特性的分子亚单位。有了这一续期奖,合成有机计划将支持弗吉尼亚大学化学系的詹姆斯·A·马歇尔博士的研究。马歇尔教授将专注于开发制备醇的方法,特别是烯丙醇和高丙叉醇,这些醇可以作为亚单位来构建具有有趣生物学特性的分子。
英文摘要
The focus of this research will be the development of synthetic methodology using chiral allenylmetallic reagents of tin, boron, titanium, chromium and palladium. Particular attention will be placed on electrophilic substitution additions to aldehydes as a route to enantioenriched propargylic and allenic carbinols. Elaboration of the carbinols will permit the synthesis of subunits of molecules that have important biological properties. With this renewal award, the Synthetic Organic Program is supporting the research of Dr. James A. Marshall of the Department of Chemistry at the University of Virginia. Professor Marshall will focus his work on the development of methods for the preparation of alcohols, specifically allenylcarbinols and homopropargylic alcohols, that can serve as subunits for the construction of molecules having interesting biological properties.
期刊论文(0)
专著(0)
科研奖励(0)
会议论文
Collaborative Research: The AGEP California Hispanic Serving Institutions (HSI) Alliance to Increase Underrepresented Minority Faculty in STEM
Brains on Board: Neuromorphic Control of Flying Robots
  • 批准号:
    EP/P006094/1
  • 项目类别:
    Research Grant
  • 资助金额:
    $615.41万
  • 财政年份:
    2016
  • 负责人:
    James Marshall
  • 依托单位:
Green Brain: Computational Modelling of the Honeybee Brain
  • 批准号:
    EP/J019534/1
  • 项目类别:
    Research Grant
  • 资助金额:
    $84.17万
  • 财政年份:
    2013
  • 负责人:
    James Marshall
  • 依托单位:
Optimal Collective Decision-Making in Social Insects
  • 批准号:
    BB/G02166X/2
  • 项目类别:
    Research Grant
  • 资助金额:
    $40.74万
  • 财政年份:
    2010
  • 负责人:
    James Marshall
  • 依托单位:
国内基金
海外基金
晶态桥联聚倍半硅氧烷的自导向组装(self-directed assembly)及其发光性能
  • 批准号:
    21171046
  • 项目类别:
    面上项目
  • 资助金额:
    55.0万元
  • 批准年份:
    2011
  • 负责人:
    李焕荣
  • 依托单位: