U.S.-Chile Cooperative Research: Excited State Dynamics of Rutherium (II) and Rhenium (I) Complexes Containing Fused Poly-aromatic Acceptor Ligands

美国-智利合作研究：含有稠合多芳香族受体配体的钌 (II) 和铼 (I) 配合物的激发态动力学

• 批准号: 9704277
• 负责人: Thomas Meyer
• 金额: $ 2.62万
• 依托单位: University of North Carolina at Chapel Hill
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1997
• 资助国家: 美国
• 起止时间: 1997-07-01 至 2000-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9704277&HistoricalAwards=false
• 关键词: U.S.; Chile; Cooperative; Research; Excited

9704277 Meyer This Americas Program award will support Dr. Thomas J Meyer, University of North Carolina, Chapel Hill, in a research collaboration with Dr. Barbara Loeb, Pontificia Universidad Catolica de Chile, to investigate the relationship between complex structure and excited-state lifetimes. The major thrust of the study will focus on the design, synthesis, and characterization of a novel class of chemical complexes. The researchers plan to conduct detailed excited state studies, which will include energy gap law correlations and molecular orbital calculations on acceptor ligands. The role of rigidity, delocalization, and redox characteristics will be investigated to determine the excited state behavior of a series of these complexes. The results of this study are expected to have an important bearing upon the rational design of compounds for application in advanced materials. The research will benefit from the combined expertise of the collaborators. The distinct synthesis expertise and computational abilities of the Chilean research group complements the US group's strength in molecular design and photophysical characterization. ***

小行星9704277 这个美洲计划奖将支持查佩尔山的北卡罗来纳州大学的托马斯J迈耶博士， 与智利天主教大学的Barbara Loeb博士合作研究复杂结构与激发态寿命之间的关系。的主要目标 的 研究将集中在设计，合成， 和表征一类新的化学络合物。 研究人员计划进行详细的激发态研究，其中将包括能隙定律相关性和分子轨道计算 在受体配体上。 的作用 的 刚性，离域，和氧化还原特性将被研究，以确定一系列这些络合物的激发态行为。 本研究的结果有望对先进材料中化合物的合理设计产生重要影响。 这项研究将受益于合作者的综合专业知识。 的 不同 合成 专门知识 智利研究小组的计算能力补充了美国研究小组在分子设计和生物物理表征方面的实力。 ***