Purchase of a Single Crystal X-Ray Diffraction System

购买单晶X射线衍射系统

• 批准号: 8919288
• 负责人: Thomas Meyer
• 金额: $ 22.66万
• 依托单位: University of North Carolina at Chapel Hill
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1989
• 资助国家: 美国
• 起止时间: 1989-11-15 至 1992-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8919288&HistoricalAwards=false
• 关键词: Purchase; Single; Crystal; Ray; Diffraction

Single crystal x-ray crystallography is the most powerful analytical method for structure determination of solids. In synthetic inorganic, organic, bioinorganic and organometallic chemistry, single crystal x-ray diffraction is an invaluable tool to characterize molecular structure. The information gained from the knowledge of the intermolecular composition and structure helps to develop new reactions of potentially general interest in catalysis or organic synthesis. This award from the Chemistry Shared Instrumentation Program will help the Department of Chemistry and the University of North Carolina in Chapel Hill to acquire a Single Crystal X-Ray Diffraction System. Among the areas of chemical research that will be enhanced by the acquisition are the following: 1. Studies of Metal Oxo Complexes 2. Synthesis, Reactivity, and Spectroscopy of Copper Complexes 3. Phase Transitions in Linear Chain Compounds 4. Metallophosphine and Metalloarsine Compounds 5. Organic Transformation of Coordinated Ligands 6. Organometallic Chemistry

单晶 X 射线晶体学是确定固体结构的最强大的分析方法。 在合成无机、有机、生物无机和有机金属化学中，单晶 X 射线衍射是表征分子结构的宝贵工具。 从分子间组成和结构的知识中获得的信息有助于开发催化或有机合成中具有潜在普遍意义的新反应。 化学共享仪器计划的这一奖项将帮助化学系和北卡罗来纳大学教堂山分校获得单晶 X 射线衍射系统。 此次收购将增强的化学研究领域如下： 1. 金属氧配合物的研究 2. 铜配合物的合成、反应性和光谱学 3. 直链化合物中的相变 4. 金属膦和金属胂化合物 5. 配位配体的有机转化 6. 有机金属化学