Studies of Monolayer Protected Metal Clusters and of Electron Transfer Active Molecular Melts
单层保护金属簇和电子转移活性分子熔体的研究
基本信息
- 批准号:9726171
- 负责人:
- 金额:$ 88.2万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Standard Grant
- 财政年份:1998
- 资助国家:美国
- 起止时间:1998-01-01 至 2000-12-31
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
This renewal project, supported in the Analytical and Surface Chemistry Program, aims to synthesize and characterize the chemical and electrochemical behavior of monolayer-protected nanoscopic metal clusters and of novel, mixed valent solid and semi-solid molecular melt phases. Professor Murray and his students at the University of North Carolina at Chapel Hill will use a wide range of experimental methods in this work including nuclear magnetic resonance, Fourier transform infrared red, thermal, fluorescence, and mass spectroscopy together with electrochemical techniques and conductivity measurements. These new interfacial materials with nanoscopic dimensions hold technological promise in electrocatalysis, molecular devices, and electrochromic materials. Novel thin-film materials incorporating nanoscopic gold clusters and involving electroactive molecular melts prepared from polyether oligomers that exhibit polymer-like solid and semi-solid properties will be studied. Professor Murray and his students at the University of North Carolina at Chapel Hill will pursue studies of these materials using a wide range of experimental techniques while considering the applicability of these materials in the fields of electrocatalysis, electrochromic devices, and novel chemical reagents. This work blends fundamental work in chemistry while keeping clear goals to develop materials with technological relevance and societal value.
这个更新项目,在分析和表面化学计划的支持下,旨在合成和表征单层保护的纳米级金属簇的化学和电化学行为,以及新型的混合价固体和半固体分子熔体相。 Murray教授和他在查佩尔山的北卡罗来纳州大学的学生将在这项工作中使用广泛的实验方法,包括核磁共振,傅立叶变换红外,热,荧光和质谱,以及电化学技术和电导率测量。 这些具有纳米尺寸的新型界面材料在电催化、分子器件和电致变色材料中具有技术前景。 将研究包含纳米级金簇并涉及由聚醚低聚物制备的电活性分子熔体的新型薄膜材料,这些材料表现出类似聚合物的固体和半固体性质。 Murray教授和他在查佩尔山的北卡罗来纳州大学的学生将使用广泛的实验技术对这些材料进行研究,同时考虑这些材料在电催化,电致变色器件和新型化学试剂领域的适用性。 这项工作融合了化学的基础工作,同时保持明确的目标,开发具有技术相关性和社会价值的材料。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
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Royce Murray其他文献
Royce Murray的其他文献
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{{ truncateString('Royce Murray', 18)}}的其他基金
MEDIATED ELECTROCATALYSIS WITH AND ANALYTICAL CHEMISTRY OF NANOPARTICLES
纳米粒子介导的电催化和分析化学
- 批准号:
0950320 - 财政年份:2010
- 资助金额:
$ 88.2万 - 项目类别:
Continuing Grant
Chemistry and Electrochemistry of Nanoparticles From Metal to Molecule-Like
纳米粒子从金属到类分子的化学和电化学
- 批准号:
0645925 - 财政年份:2007
- 资助金额:
$ 88.2万 - 项目类别:
Continuing Grant
Chemistry and Electrochemistry of Molecule-Like Nanoparticles
类分子纳米粒子的化学和电化学
- 批准号:
0350287 - 财政年份:2004
- 资助金额:
$ 88.2万 - 项目类别:
Continuing Grant
Chemistry and Electrochemistry of Molecular Nanoparticles and Molecular Melts
分子纳米颗粒和分子熔体的化学和电化学
- 批准号:
0091788 - 财政年份:2001
- 资助金额:
$ 88.2万 - 项目类别:
Continuing Grant
Studies of Electron Transfer Active Polymers, Polymer Solutions, and Proteins
电子转移活性聚合物、聚合物溶液和蛋白质的研究
- 批准号:
9222186 - 财政年份:1993
- 资助金额:
$ 88.2万 - 项目类别:
Continuing Grant
Design, Characterization, and Electron Hopping Properties ofThin Molecular Films
分子薄膜的设计、表征和电子跳跃特性
- 批准号:
9221118 - 财政年份:1993
- 资助金额:
$ 88.2万 - 项目类别:
Standard Grant
Design and Characterization of Molecular Films
分子膜的设计和表征
- 批准号:
8918506 - 财政年份:1990
- 资助金额:
$ 88.2万 - 项目类别:
Continuing Grant
Chemical and Spatial Design of Polymer Films on Electrodes
电极上聚合物薄膜的化学和空间设计
- 批准号:
8715403 - 财政年份:1988
- 资助金额:
$ 88.2万 - 项目类别:
Continuing Grant
Design and Characterization of Molecular Films
分子膜的设计和表征
- 批准号:
8709906 - 财政年份:1987
- 资助金额:
$ 88.2万 - 项目类别:
Continuing Grant
Chemical and Spatial Design of Electroactive Polymer Membranes on Electrodes
电极上电活性聚合物膜的化学和空间设计
- 批准号:
8413450 - 财政年份:1985
- 资助金额:
$ 88.2万 - 项目类别:
Continuing Grant
相似海外基金
On Heavier Chalcogen (Se and Te) Interfacial Chemistry and Charge Transfer in Monolayer-Protected Metal Nanoparticles
单层保护金属纳米粒子中重硫族元素(Se 和 Te)界面化学和电荷转移
- 批准号:
1413429 - 财政年份:2014
- 资助金额:
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International Symposium on Monolayer-Protected Clusters (ISMPC13)
单层保护团簇国际研讨会(ISMPC13)
- 批准号:
1339545 - 财政年份:2013
- 资助金额:
$ 88.2万 - 项目类别:
Standard Grant
GOALI: Semi-Packed Gas Separation Columns with Monolayer-Protected Gold Phases
GOALI:具有单层保护金相的半填充气体分离柱
- 批准号:
1002279 - 财政年份:2010
- 资助金额:
$ 88.2万 - 项目类别:
Continuing Grant
Postsynthetic asymmetric transformation of monolayer-protected metal nanoclusters and their chiroptical responses
单层保护金属纳米团簇的合成后不对称转变及其手性光学响应
- 批准号:
22510104 - 财政年份:2010
- 资助金额:
$ 88.2万 - 项目类别:
Grant-in-Aid for Scientific Research (C)
CAREER: Undergraduate research on the properties and mechanistic studies of organic molecules assembled on monolayer protected clusters
职业:本科生研究单层保护簇上组装的有机分子的性质和机理研究
- 批准号:
0738937 - 财政年份:2007
- 资助金额:
$ 88.2万 - 项目类别:
Continuing Grant
CAREER: Undergraduate research on the properties and mechanistic studies of organic molecules assembled on monolayer protected clusters
职业:本科生研究单层保护簇上组装的有机分子的性质和机理研究
- 批准号:
0643709 - 财政年份:2007
- 资助金额:
$ 88.2万 - 项目类别:
Continuing grant
Monolayer protected gold clusters as oxidation catalysts
单层保护的金簇作为氧化催化剂
- 批准号:
352518-2007 - 财政年份:2007
- 资助金额:
$ 88.2万 - 项目类别:
University Undergraduate Student Research Awards
Electronic Structures and Photoluminescence of Monolayer-Protected Metal Clusters
单层保护金属团簇的电子结构和光致发光
- 批准号:
16510079 - 财政年份:2004
- 资助金额:
$ 88.2万 - 项目类别:
Grant-in-Aid for Scientific Research (C)
Monolayer Protected Nanoparticles Flavoenzyme Models
单层保护纳米粒子黄素酶模型
- 批准号:
6729036 - 财政年份:1999
- 资助金额:
$ 88.2万 - 项目类别:
Monolayer Protected Nanoparticles Flavoenzyme Models
单层保护纳米粒子黄素酶模型
- 批准号:
6621195 - 财政年份:1999
- 资助金额:
$ 88.2万 - 项目类别: