Nanoscale Molecular Architecture via Metal Directed Coordination Driven Self-Assembly

通过金属定向配位驱动自组装的纳米级分子结构

• 批准号: 9818472
• 负责人: Peter Stang
• 金额: $ 40.6万
• 依托单位: University of Utah
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1999
• 资助国家: 美国
• 起止时间: 1999-06-01 至 2003-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9818472&HistoricalAwards=false
• 关键词: Nanoscale; Molecular; Architecture; via; Metal

With this renewal award the Organic and Macromolecular Chemistry Program continues its support for the work of Dr. Peter Stang in the Department of Chemistry at the University of Utah. The research extends his earlier work on making metallocyclic supramolecular squares to preparing a variety of more complex molecular architectures, including pentagons, hexagons, cubes, octahedra, , dodecahedra, and adamantanoids. These structures self-assemble as a result of relatively strong bonds between transition metals and ligating atoms in the molecular subassemblies, and can be constructed with precisely defined shapes and sizes.If fully successful, this research will lead to novel solid state materials useful for a variety of applications, including catalysts, sensors, and electronic materials.

有了这一续签奖，有机和大分子化学计划继续支持彼得·斯坦博士在犹他大学化学系的工作。 这项研究扩展了他早期在制作金属菌性超分子正方形方面的工作，以准备各种更复杂的分子体系结构，包括五角星，六角形，立方体，八人，八人，十二卷，十二烷和阿amantanoids。 这些结构是由于过渡金属和分子亚构造中的连接原子之间相对较强的键而自组装的，并且可以用精确定义的形状和大小来构建。如果完全成功，这项研究将导致新的固态材料对包括各种应用，包括催化剂，传感器和电子材料。