Equilibrium Dynamics of Dense Colloids and Polymers: X-ray Photon Correlation Spectroscopy Studies

致密胶体和聚合物的平衡动力学：X 射线光子相关光谱研究

• 批准号: 0071755
• 负责人: Simon Mochrie
• 金额: $ 42.3万
• 依托单位: Massachusetts Institute of Technology
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2000
• 资助国家: 美国
• 起止时间: 2000-05-15 至 2004-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0071755&HistoricalAwards=false
• 关键词: Equilibrium; Dynamics; Dense; Colloids; Polymers

This is an experimental condensed matter physics project that will investigate the dynamical properties of colloids, polymers and related fluids, commonly termed soft mattes. While the static structure of soft matter has been extensively examined, the dynamical properties on the most relevant length scales (10-100 nm) have been much more difficult to study. This project will yield new insight into the collective dynamics of soft materials, with particular emphasis on concentrated and entangled systems. To achieve the scattering wave vectors required, the emerging technique of x-ray photon correlation spectroscopy (XPCS) will be employed. The role of hydrodynamic interactions and entanglements in the dynamics of isotropic suspensions of colloidal rods will also be studied. Dynam-ical critical behavior near the colloidal liquid-colloidal gas critical point in colloid/polymer mixtures is another topic of interest. Understanding how a divergent viscosity, predicted for this dynamic universality class, affects the dynamics on length scales comparable to the inter-particle separation will improve our understanding of protein crystallization. The dynamics of entangled polymer systems will be investigated and compared to relevant theories. Importantly, these investigations will provide quantitative tests of the reptation model of polymer dynamics in the previously-inaccessible regime of long times, short distances, and flexible poly-mers. Students trained under this project will contribute to the pool of talent needed to fully utilize this nation's major investment in synchrotron-radiation-based research. In addition, the further development of x-ray photon correlation spectroscopy under this program will contribute to the scientific case for a new generation of even-more-powerful x-ray sources.%%%Complex fluids, such as fine dispersions of solid particles within a fluid (colloidal dispersions), blends of long-chain polymers, and mixtures of oil, water and soap are an important class of materials, commonly termed "soft matter". While the static structure of such soft materials has been studied extensively, the molecular motions of complex fluids have been much more difficult to study. In this project, a novel synchrotron-based x-ray scatter-ing method - x-ray photon correlation spectroscopy - will be used to examine very slow motions on small distances, and should yield new insight into the thermal movements within colloidal and polymeric systems. Comparisons between the results obtained and available theories will provide a critical test of the theories. The insights gained may be practically important for improved understanding and control of such diverse phenomena as protein crystallization or the flow of polymeric fluids. Students trained to carry out cutting-edge x-ray scattering research under this program will contribute to the pool of talent needed to make use of this nation's major investment in synchrotron-radiation-based research. The graduates will be well-prepared to carry out academic, industrial, or governmental research. The further development of x-ray photon correlation spectroscopy under this program will contribute to the scientific case for a new generation of even-more-powerful x-ray sources.

这是一个实验凝聚态物理项目，将研究胶体，聚合物和相关流体的动力学特性，通常称为软物质。虽然软物质的静态结构已被广泛研究，但最相关长度尺度（10-100纳米）上的动力学性质却很难研究。该项目将产生新的洞察力的集体动力学的软材料，特别强调集中和纠缠系统。为了获得所需的散射波矢量，将采用新兴的X射线光子相关光谱（XPCS）技术。流体动力学的相互作用和纠缠的胶体棒的各向同性悬浮液的动力学中的作用也将进行研究。胶体/聚合物混合物中胶体-液体-胶体-气体临界点附近的动力学临界行为是另一个令人感兴趣的课题。了解如何发散的粘度，预测这个动态的普遍性类，影响动态的长度尺度可比的粒子间分离将提高我们对蛋白质结晶的理解。纠缠聚合物系统的动力学将被研究并与相关理论进行比较。重要的是，这些调查将提供定量测试的爬行模型的聚合物动力学在以前无法访问的制度的长时间，短距离，和灵活的聚合物。在这个项目下培训的学生将有助于充分利用这个国家在同步辐射研究方面的主要投资所需的人才库。此外，在该计划下，X射线光子相关光谱学的进一步发展将有助于新一代更强大的X射线源的科学案例。复杂的流体，例如固体颗粒在流体中的精细分散体（胶体分散体）、长链聚合物的共混物以及油、水和肥皂的混合物，是一类重要的材料，通常被称为“软物质”。虽然此类软材料的静态结构已被广泛研究，但复杂流体的分子运动却很难研究。在这个项目中，一种新的基于同步加速器的X射线散射方法-X射线光子相关光谱学-将被用来检查在小距离上的非常慢的运动，并应该产生新的洞察力胶体和聚合物系统内的热运动。所得结果与现有理论的比较将为理论提供一个关键的检验。所获得的见解可能是实际上重要的，以提高理解和控制等不同的现象，如蛋白质结晶或聚合物流体的流动。根据该计划，接受培训以进行尖端x射线散射研究的学生将为利用国家在同步辐射研究方面的重大投资所需的人才库做出贡献。毕业生将为开展学术，工业或政府研究做好充分准备。该计划下X射线光子相关光谱学的进一步发展将有助于新一代更强大的X射线源的科学案例。