Macromolecular Architecture and Properties

PI计划完成杂化无机陶瓷材料和导电聚苯胺的制备。陶瓷材料为多孔沸石（沸石13X和沸石5A）和蒙脱土粘土。将制备聚（2,6-甲基-1,4-苯基氧化物）和聚苯胺的互穿聚合物网络以及内部涂有聚苯胺的聚氨酯泡沫，并通过透射和扫描差热法，直流电导率和esr光谱来确定它们的磁性能。将完成一些与聚合物有关的平衡和非平衡密度泛函研究的理论研究，以及与聚合物粘度有关的一些输运问题的研究。本研究属于重要杂化材料的理论和实验研究领域。

The PI plans to finish the preparation of hybrid inorganic ceramic materials and electrically conductive polyaniline. The ceramic materials are porous zeolites(zeolite 13X and zeolite 5A) and montmorillonite clays. Interpenetrating polymer networks of poly(2,6-methyl-1,4-phenylene oxide) and polyaniline as well as polyurethane foams coated internally with polyaniline will be prepared and by transmission and scanning differential calorimetry, DC electrical conductivities, and E.S.R. spectroscopy to determine also their magnetic properties. Theoretical studies of a number of equilibrium and non-equilibrium density functional studies related to polymers as well as investigations of some transport problems related to polymer viscosity, will be completed. %%%This research is in the area of theoretical and experimental investigations of important hybrid materials.