Macromolecular Architecture and Properties

高分子结构和性质

• 批准号: 0098780
• 负责人: Harry Frisch
• 金额: $ 4.2万
• 依托单位: SUNY at Albany
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2001
• 资助国家: 美国
• 起止时间: 2001-05-01 至 2002-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0098780&HistoricalAwards=false
• 关键词: Macromolecular; Architecture; Properties

The PI plans to finish the preparation of hybrid inorganic ceramic materials and electrically conductive polyaniline. The ceramic materials are porous zeolites(zeolite 13X and zeolite 5A) and montmorillonite clays. Interpenetrating polymer networks of poly(2,6-methyl-1,4-phenylene oxide) and polyaniline as well as polyurethane foams coated internally with polyaniline will be prepared and by transmission and scanning differential calorimetry, DC electrical conductivities, and E.S.R. spectroscopy to determine also their magnetic properties. Theoretical studies of a number of equilibrium and non-equilibrium density functional studies related to polymers as well as investigations of some transport problems related to polymer viscosity, will be completed. %%%This research is in the area of theoretical and experimental investigations of important hybrid materials.

PI计划完成杂化无机陶瓷材料和导电聚苯胺的制备。 陶瓷材料是多孔沸石（沸石13 X和沸石5A）和蒙脱石粘土。 制备了聚（2，6-甲基-1，4-苯醚）和聚苯胺的互穿聚合物网络以及内部涂有聚苯胺的聚氨酯泡沫，并通过透射和扫描差热法、直流电导率和E.S.R.光谱，以确定其磁性。 将完成一些与聚合物有关的平衡和非平衡密度泛函研究的理论研究以及与聚合物粘度有关的一些运输问题的调查。这项研究是在重要的杂化材料的理论和实验研究领域。