Kinetics and Mechanisms: Oxidation of Some Selected Sulfur Compounds of Physiological and Environmental Importance

动力学和机制：一些选定的具有生理和环境重要性的硫化合物的氧化

• 批准号: 0137435
• 负责人: Reuben Simoyi
• 金额: $ 33万
• 依托单位: West Virginia University Research Corporation
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2002
• 资助国家: 美国
• 起止时间: 2002-05-01 至 2003-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0137435&HistoricalAwards=false
• 关键词: Kinetics; Mechanisms; Oxidation; Some; Selected

This grant by the Inorganic, Bioinorganic and Organometallic Chemistry Program supports work by Professor Reuben H. Simoyi at West Virginia University to investigate the reaction mechanisms of small organic sulfur compounds. Focus areas are: S-oxygenation, enzymatic and nonenzymatic metabolic activation, radical species, decomposition and autoxidation reactions, and toxicity effects. These areas of investigation relate to important physiological, environmental and industrial processes involving oxidation, C-S bond cleavage and radical intermediates.Reactions of sulfur compounds will be studied, particularly with regard to their utility in understanding sulfur reactivities in physiological, environmental and industrial processes.

这项由无机、生物无机和有机化学项目资助的研究由Reuben H.西弗吉尼亚大学的Simoyi研究了小分子有机硫化合物的反应机理。 重点领域是：氧化、酶和非酶代谢活化、自由基、分解和自氧化反应以及毒性效应。 这些研究领域涉及重要的生理，环境和工业过程，包括氧化，C-S键断裂和自由基中间体。含硫化合物的反应将被研究，特别是关于它们在理解生理，环境和工业过程中的硫反应性方面的效用。