Kinetics and Mechanisms: Oxidation of Some Selected Sulfur Compounds of Physiological and Environmental Importance

该基金由无机、生物无机和有机金属化学项目资助，支持西弗吉尼亚大学Reuben H. Simoyi教授研究小有机硫化合物的反应机制。重点领域是：s -氧合，酶和非酶代谢激活，自由基种类，分解和自氧化反应，以及毒性作用。这些研究领域涉及重要的生理、环境和工业过程，涉及氧化、C-S键裂解和自由基中间体。硫化合物的反应将被研究，特别是关于它们在理解生理，环境和工业过程中的硫反应的效用。

This grant by the Inorganic, Bioinorganic and Organometallic Chemistry Program supports work by Professor Reuben H. Simoyi at West Virginia University to investigate the reaction mechanisms of small organic sulfur compounds. Focus areas are: S-oxygenation, enzymatic and nonenzymatic metabolic activation, radical species, decomposition and autoxidation reactions, and toxicity effects. These areas of investigation relate to important physiological, environmental and industrial processes involving oxidation, C-S bond cleavage and radical intermediates.Reactions of sulfur compounds will be studied, particularly with regard to their utility in understanding sulfur reactivities in physiological, environmental and industrial processes.