Collaborative Research: Surface and Actuation Kinetics of Stimulus-Responsive Hydrogels

合作研究：刺激响应水凝胶的表面和驱动动力学

• 批准号: 0324553
• 负责人: Eliot Fried
• 金额: $ 12.89万
• 依托单位: Washington University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2003
• 资助国家: 美国
• 起止时间: 2003-09-01 至 2006-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0324553&HistoricalAwards=false
• 关键词: Collaborative; Research; Surface; Actuation; Kinetics

AbstractA collaborative effort between researchers at Duke University and Washington University is supported to investigate the surface and actuation kinetics of stimulus responsive hydrogels (SRHs). These materials are polymer gels that exhibit a large change in volume and surface physiochemical properties during a reversible phase transition. SRHs have the potential to overcome some of the fundamental limitations of micro-actuation and sensing devices that currently use electromagnetic or piezoelectric actuators. The overall characteristics of SRHs point toward devices that are biocompatible, operate with minimal power input, and provide a range of motion that is difficult to achieve with existing servomechanisms. The proposed work will combine experiment, theory, and computation with the goal of advancing technologies based on these multifunctional materials. Experiments to be conducted at Duke will include: 1) optical measurements of volume displacement changes in SRHs using a novel optical-mechanical setup; 2) tribological measurements of SRHs using a parallel-disk rheometer; and 3) fine-grained, spatially resolved force adhesion and friction force maps using colloidal probe microscopy. In conjunction with these efforts, researchers at Washington University will develop physically consistent bulk and interfacial constitutive models. Finally, numerical simulations of some of the experiments will be conducted at both institutions to correlate material parameters and gain predictive capabilities for rational design with SRHs.

摘要杜克大学和华盛顿大学的研究人员合作研究了刺激响应水凝胶（SRH）的表面和致动动力学。 这些材料是聚合物凝胶，在可逆相变期间表现出体积和表面物理化学性质的大变化。 SRH有可能克服目前使用电磁或压电致动器的微致动和传感设备的一些基本限制。 SRH的总体特征指向具有生物相容性的装置，以最小的功率输入操作，并提供难以用现有伺服机构实现的运动范围。 拟议的工作将结合联合收割机的实验，理论和计算的目标，推进基于这些多功能材料的技术。 在杜克进行的实验将包括：1）使用新型光学机械装置对SRH中的体积位移变化进行光学测量; 2）使用平行盘流变仪对SRH进行摩擦学测量; 3）使用胶体探针显微镜进行细粒度、空间分辨力粘附和摩擦力图。 与这些努力相结合，华盛顿大学的研究人员将开发物理上一致的体积和界面本构模型。 最后，一些实验的数值模拟将在这两个机构进行相关的材料参数，并获得合理设计与SRH的预测能力。