CAREER: New Vistas in Early-Transition Metal Complexes Containing Metal-Ligand Multiple Bonds
职业生涯:含有金属-配体多重键的早期过渡金属配合物的新前景
基本信息
- 批准号:0348941
- 负责人:
- 金额:$ 50万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Continuing Grant
- 财政年份:2004
- 资助国家:美国
- 起止时间:2004-01-15 至 2008-12-31
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
This CAREER award in the Inorganic, Bioinorganic and Organometallic Chemistry program supports work by Professor Daniel J. Mindiola at Indiana University to explore the chemistry of three- and four-coordinate titanium complexes having metal-ligand multiple bonds. The research involves the synthesis, structure, reactivity, and kinetic studies of a four-coordinate titanium(IV) alkylidene, imide, and phosphinidene complexes. Topics addressed include bonding considerations and mechanistic and reactivity studies of titanium alkylidene, imide, and phosphinidene systems. Investigations extend to group 5 complexes and redox studies stemming from vanadium complexes containing metal-ligand multiple bonds. Specific targets of the project are to: i) Prepare low-coordinate and high-oxidation state early-transition metal complexes containing metal-ligand multiple bonds. ii) Explore the reactivity of these unique systems and compare catalytic activity with well-established systems. iii) Expand this synthetic methodology to the preparation of low-coordinate group 3 and 5 transition metals. iv) Through retro-analytical concept mapping and self-assessment techniques, recruit undergraduate students in basic science-oriented research. v) Implement two student-based chapters at Indiana University for the recruitment of minority groups into the physical sciences. This work aims toward new catalysts by exploring new transition metal complexes with multiple bonds. The education plan is to develop undergraduate research awareness and implementation of student-based chapters for the recruitment of undergraduates (especially from underrepresented groups) into the physical sciences.
无机,生物无机和有机化学计划的职业奖支持印第安纳州大学的丹尼尔J. Mindiola教授的工作,以探索具有金属配体多重键的三配位和四配位钛络合物的化学。 本研究包括四配位钛(IV)烷叉、酰亚胺和膦叉配合物的合成、结构、反应性和动力学研究。讨论的主题包括键合的考虑和机制和钛烷叉,酰亚胺和膦系统的反应性研究。 调查扩展到第5组复合物和氧化还原研究源于钒配合物含有金属配体多重键。该项目的具体目标是:i)制备含有金属配体多重键的低配位和高氧化态的前过渡金属配合物。 ii)探索这些独特系统的反应性,并将催化活性与成熟系统进行比较。 iii)将这种合成方法扩展到低配位的第3族和第5族过渡金属的制备。 ㈣通过追溯分析概念图和自我评估技术,招收本科生从事基础科学研究。 v)在印第安纳州大学实施两个以学生为基础的章节,以招募少数群体进入物理科学领域。本工作旨在通过探索新的具有多键的过渡金属配合物来开发新的催化剂。 教育计划是培养本科生的研究意识,并实施以学生为基础的章节,以招募本科生(特别是来自代表性不足的群体)进入物理科学。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
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Daniel Mindiola其他文献
Daniel Mindiola的其他文献
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{{ truncateString('Daniel Mindiola', 18)}}的其他基金
CAS: Synthetic Entries to ETM with M-Ligand Multiple Bonds and Their Role in Stoichiometric and Catalytic Carbon-Hydrogen Activation and Functionalization of Volatile Alkanes
CAS:具有 M 配体多重键的 ETM 合成条目及其在挥发性烷烃的化学计量和催化碳氢活化和官能化中的作用
- 批准号:
2154620 - 财政年份:2022
- 资助金额:
$ 50万 - 项目类别:
Standard Grant
MRI: Acquisition of an X-ray Absorption Fine Structure (XAFS) source for Chemical and Spectroscopic Research and Training at the University of Pennsylvania
MRI:宾夕法尼亚大学购买 X 射线吸收精细结构 (XAFS) 源用于化学和光谱研究和培训
- 批准号:
2117783 - 财政年份:2021
- 资助金额:
$ 50万 - 项目类别:
Standard Grant
Constructing Metal-Carbon Multiple Bonds for Dehydrogenation and Dehydrocoupling Reactions Involving Volatile Hydrocarbons
构建涉及挥发性碳氢化合物的脱氢和脱氢偶联反应的金属-碳多重键
- 批准号:
1764329 - 财政年份:2018
- 资助金额:
$ 50万 - 项目类别:
Continuing Grant
Metal-Ligand Multiple Bonds, Dehydrogenation Chemistry and Catalytic Transformations of Small Molecules Such as Methane, Ethane, Other Hydrocarbons, and N2
甲烷、乙烷、其他碳氢化合物和氮气等小分子的金属配体多重键、脱氢化学和催化转化
- 批准号:
1464659 - 财政年份:2015
- 资助金额:
$ 50万 - 项目类别:
Continuing Grant
Metal-Ligand Multiple Bonds and Their Role in Alkane Metathesis, Dehydrogenation and Group-Transfer Chemistry
金属配体多重键及其在烷烃复分解、脱氢和基团转移化学中的作用
- 批准号:
1413945 - 财政年份:2013
- 资助金额:
$ 50万 - 项目类别:
Standard Grant
Metal-Ligand Multiple Bonds and Their Role in Alkane Metathesis, Dehydrogenation and Group-Transfer Chemistry
金属配体多重键及其在烷烃复分解、脱氢和基团转移化学中的作用
- 批准号:
1152123 - 财政年份:2012
- 资助金额:
$ 50万 - 项目类别:
Standard Grant
Synthetic Entries to Early-Transition Metal Complexes Containing Terminal and Reactive Metal-Ligand Multiple Bonds
含有末端和活性金属-配体多重键的早期过渡金属配合物的合成
- 批准号:
0848248 - 财政年份:2009
- 资助金额:
$ 50万 - 项目类别:
Continuing Grant
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