Kinetics of reductive amination and hydroaminomethylation in reactive multiphase fluid systems (A03)

反应性多相流体体系中还原胺化和氢氨甲基化的动力学 (A03)

• 批准号: 166344380
• 金额: --
• 依托单位: Max-Planck-Institut für Dynamik komplexer technischer Systeme
• 依托单位国家: 德国
• 项目类别: CRC/Transregios
• 财政年份: 2010
• 资助国家: 德国
• 起止时间: 2009-12-31 至 2020-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/166344380?language=en
• 关键词: Kinetics; reductive; amination; hydroaminomethylation; reactive

The focus of the project is the experimental and theoretical studies on the mechanism and kinetics of the reductive amination of long-chain aldehydes and hydroaminomethylation. The aim is to systemati-cally elucidate the reaction networks and catalytic cycles, to derive and reduce kinetic models and to determine the model parameters with great precision. This provides the basis for the design of reac-tors and processes. In addition, general rules for the evaluation of tandem reactions (multi-pot vs. single-pot synthesis) are developed.

本项目的重点是长链醛的还原胺化反应和氢氨甲基化反应的机理和动力学的实验和理论研究。目的是系统地阐明反应网络和催化循环，推导和简化动力学模型，并精确地确定模型参数。这为反应器和工艺的设计提供了依据。此外，开发了评价串联反应（多锅与单锅合成）的一般规则。