Solid State Coordination Chemistry of Metal Oxide Hybrid Materials

金属氧化物杂化材料的固态配位化学

• 批准号: 0604527
• 负责人: Jon Zubieta
• 金额: $ 41.93万
• 依托单位: Syracuse University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2006
• 资助国家: 美国
• 起止时间: 2006-06-01 至 2010-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0604527&HistoricalAwards=false
• 关键词: Solid; State; Coordination; Chemistry; Metal

Professor Jon A. Zubieta of Syracuse University is supported by the Inorganic, Bioinorganic and Organometallic Chemistry Program to explore the synthesis of hybrid metal oxide crystals in hydrothermal media. These metal oxides are capable of incorporating organic components in their crystalline phases and thus the design and discovery facets of the project elaborate on the understanding of the role of structural determinants on thermal stability and pore dimensions of the novel oxovanadium and oxomolybdenum phosphonates and related materials. The microporous properties of these materials are of considerable interest for applications in separation and gas storage, catalysis, and non-linear optics. Undergraduate and graduate students will be involved in this interdisciplinary research, conducting the proposed chemical syntheses and property measurements. Professor Zubieta will develop instructional materials for graduate students in the form of a two-semester sequence devoted to x-ray crystallography and structural solid state chemistry as well as a website on crystallographic principles. These instructional materials have been adapted for presentation to high school teachers and students participating in the Syracuse University Project Advance.

Jon A.锡拉丘兹大学的Zubieta得到了无机、生物无机和有机化学项目的支持，探索在水热介质中合成混合金属氧化物晶体。 这些金属氧化物能够将有机成分纳入其晶相，因此该项目的设计和发现方面阐述了对新型氧钒和氧钼膦酸盐及相关材料的热稳定性和孔尺寸的结构决定因素的作用的理解。 这些材料的微孔性质在分离和气体储存、催化和非线性光学中的应用是相当感兴趣的。 本科生和研究生将参与这项跨学科的研究，进行拟议的化学合成和性能测量。 Zubieta教授将为研究生开发教学材料，以两个学期的序列形式，致力于X射线晶体学和结构固态化学以及晶体学原理网站。 这些教学材料经过改编后，将介绍给参加锡拉丘兹大学项目“前进”的高中教师和学生。