Strategies for Tailoring the Redox Properties of d6/d8-Electron Platinum and Palladium Complexes

定制 d6/d8-电子铂和钯配合物的氧化还原性能的策略

• 批准号: 0749790
• 负责人: William Connick
• 金额: $ 39万
• 依托单位: University of Cincinnati Main Campus
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2008
• 资助国家: 美国
• 起止时间: 2008-03-01 至 2012-02-29
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0749790&HistoricalAwards=false
• 关键词: Strategies; Tailoring; Redox; Properties; d6

This award in the Inorganic, Bioinorganic and Organometallic Chemistry program supports work by Professor William Connick at the University of Cincinnati to prepare transition metal two-electron reagents and elucidate the factors that govern their outer-sphere electron-transfer reactions. These studies are expected to provide the knowledge needed to develop strategies for tailoring the thermodynamics and kinetics of cooperative two-electron transfer reactions. Multielectron transfer reactions are central to many of the most important challenges in chemical synthesis and catalysis, including energy conversion and storage. Two classes of reversible two-electron transfer reagents will be investigated. A battery of physical experiments will be used to determine electronic structures, ligand fluxionality, redox thermodynamics, and rates of electron transfer. The research activities will bring together a research team composed of high school students, undergraduate students, graduate students, a postdoctoral researcher, and Professor Connick. A chemistry web site will be developed in collaboration with a Cincinnati Public Schools high school teacher.

无机，生物无机和有机化学计划的这一奖项支持辛辛那提大学的William Connick教授的工作，以制备过渡金属双电子试剂并阐明控制其外层电子转移反应的因素。 这些研究预计将提供所需的知识，制定战略，定制的热力学和动力学合作的两个电子转移反应。 多电子转移反应是化学合成和催化中许多最重要挑战的核心，包括能量转换和储存。 研究了两类可逆双电子转移试剂。 一组物理实验将用于确定电子结构，配体流动性，氧化还原热力学和电子转移速率。 研究活动将汇集一个由高中生，本科生，研究生，博士后研究员和Connick教授组成的研究团队。 一个化学网站将与辛辛那提公立学校的高中教师合作开发。