New Strategies for Catalytic C-H Bond Activation Reactions

催化C-H键活化反应的新策略

• 批准号: 1011891
• 负责人: Chae Yi
• 金额: $ 39万
• 依托单位: Marquette University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2010
• 资助国家: 美国
• 起止时间: 2010-09-01 至 2013-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1011891&HistoricalAwards=false
• 关键词: New; Strategies; Catalytic; Bond; Activation

Professor Chae S. Yi of Marquette University is supported by the Chemical Catalysis Program in the Division of Chemistry to investigate the synthetic and mechanistic aspects of transition metal-catalyzed C-H bond activation reactions. Multinuclear ruthenium-hydride catalysts will be synthesized and used to achieve this objective. Another objective of the proposed research is to design and use chiral ruthenium-oxazoline catalysts for the asymmetric C-H bond oxidation reactions.Catalytic C-H bond oxidation reactions are extensively used for the industrial production of oxygenated compounds from ubiquitous hydrocarbon compounds. The proposed research will contribute to our knowledge in homogenous catalysis, and will advance the development of energy efficient and environmentally compatible catalysts for important industrial processes. Students at Marquette University will be trained in organometallic chemistry and homogeneous catalysis and will be exposed to an international exchange experience in chemical catalysis. Minority students from Alcorn State University and the local community colleges in Milwaukee will be involved in this research.

马奎特大学化学催化计划资助马奎特大学教授研究过渡金属催化的C-H键活化反应的合成和机理。为了实现这一目标，将合成并使用多核Ru-HdH催化剂。这项研究的另一个目的是设计和使用手性Ru-Ozazoline催化剂用于不对称C-H键氧化反应。催化C-H键氧化反应被广泛用于从普遍存在的碳氢化合物工业生产含氧化合物。这项研究将有助于我们对均相催化的认识，并将促进用于重要工业过程的高效节能和环境友好的催化剂的开发。马奎特大学的学生将接受有机金属化学和均相催化方面的培训，并将接触到化学催化方面的国际交流经验。来自阿尔科恩州立大学和密尔沃基当地社区大学的少数族裔学生将参与这项研究。