Further Discovery and Elaboration of Metallacrowns

金属冠的进一步发现和精制

基本信息

项目摘要

The Chemical Structure, Dynamics and Mechanisms Program supports Professor Vincent L. Pecoraro at the University of Michigan-Ann Arbor whose research emphasizes the development of metallacrowns, metal-based molecular recognition agents that may eventually be used in applications of practical importance. Two key objectives guide the metallacrown research. The first is to understand molecular recognition of these hosts with a variety of guests in the solid state and in solution. Professor Pecoraro hopes to exploit the environment within chiral metallacrown cavities to carry out catalytic chemical transformations. The second objective seeks to exploit the solid state properties of metallacrowns to make chiral, soft non-linear optical materials, porous solids, and molecular magnets. The proposed molecular magnets, if successful, would revolutionize data storage and provide greater fundamental insight on magnetic phenomena.With the support of the Chemical Structure, Dynamics and Mechanisms Program in the Chemistry Division at the National Science Foundation, Professor Pecoraro explores the utility of metallocrowns as molecular recognition agents, catalysts, optical materials and molecular magnets. This work specifically targets the use of these materials as catalysts as well for the design of optically transparent chiral compartments for guests that display second harmonic generation for nonlinear optical materials applications. Professor Pecoraro will continue an excellent track record for producing scientists at all levels and for mentoring women and minorities in both his laboratory and the department. The PI is the Director of the Michigan Chemistry Biology Interface Training Program, which mentors second and third year graduate students and has had about 17% minority participation and 50% female trainees. The intent of this training program is to cross train students in chemistry and biology.
化学结构、动力学和机制计划支持密歇根大学安娜堡分校的文森特·L·佩科拉罗教授的研究,他的研究重点是开发金属冠醚,这是一种基于金属的分子识别剂,最终可能用于具有实际意义的应用。两个关键目标指导着金属铬合金的研究。首先是了解这些主体与各种客体在固态和溶液中的分子识别。佩科拉罗教授希望利用手性金属冠腔内的环境来进行催化化学转化。第二个目标是利用金属冠的固态特性来制造手性、柔软的非线性光学材料、多孔固体和分子磁体。Pecoraro教授在国家科学基金会化学部化学结构、动力学和机制计划的支持下,探索了金属离子作为分子识别剂、催化剂、光学材料和分子磁体的用途。这项工作特别针对这些材料作为催化剂的用途,以及为客户设计光学透明手性隔室,为非线性光学材料应用显示二次谐波产生。Pecoraro教授将继续在他的实验室和系里培养各级科学家以及指导女性和少数族裔方面的出色记录。PI是密歇根州化学生物接口培训项目的主任,该项目指导二年级和三年级的研究生,约有17%的少数族裔参与,50%的女性学员。这项培训计划的目的是交叉训练学生的化学和生物。

项目成果

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Vincent Pecoraro其他文献

Vincent Pecoraro的其他文献

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{{ truncateString('Vincent Pecoraro', 18)}}的其他基金

Synthetic Control of Lanthanide Physical Properties Using Functionalized Metallacrowns
使用功能化金属冠合成控制镧系元素物理性质
  • 批准号:
    2154116
  • 财政年份:
    2022
  • 资助金额:
    $ 51.3万
  • 项目类别:
    Standard Grant
Systematic Modulation of Lanthanide Physical Properties Using Functionalized Metallacrowns
使用功能化金属冠系统调控镧系元素物理性质
  • 批准号:
    2102046
  • 财政年份:
    2021
  • 资助金额:
    $ 51.3万
  • 项目类别:
    Standard Grant
Developing Metallacrown Scaffolds for Luminescence, Magnetism and Supramolecular Chemistry
开发用于发光、磁性和超分子化学的金属冠支架
  • 批准号:
    1664964
  • 财政年份:
    2017
  • 资助金额:
    $ 51.3万
  • 项目类别:
    Continuing Grant
Developing Magnetic, Optical and Catalytic Applications of Metallacrowns
开发金属冠的磁、光学和催化应用
  • 批准号:
    1361779
  • 财政年份:
    2014
  • 资助金额:
    $ 51.3万
  • 项目类别:
    Standard Grant
Metallacrowns: A New Class of Metallamacrocycles
金属大环:一类新的金属大环化合物
  • 批准号:
    0717098
  • 财政年份:
    2007
  • 资助金额:
    $ 51.3万
  • 项目类别:
    Continuing Grant
Metallacrowns: A New Class of Metallamacrocycles
金属大环:一类新的金属大环化合物
  • 批准号:
    0111428
  • 财政年份:
    2001
  • 资助金额:
    $ 51.3万
  • 项目类别:
    Continuing Grant
The Mechanism of Electron Transfer by an Azurin Modified by Site Directed Mutagenesis
定点诱变修饰的天青蛋白的电子转移机制
  • 批准号:
    8509583
  • 财政年份:
    1985
  • 资助金额:
    $ 51.3万
  • 项目类别:
    Standard Grant

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