Directed Assembly by Capillarity

奖项：1066284PI：StebeWe将进行基础研究，以建立各向异性毛细管组装的定量指导原则，即将颗粒形状、接触角和界面形状与相互作用的范围和强度以及形成的组装联系起来。为此，我们将从实验、数值和理论三个方面研究毛细管组装。我们已经建立了一个智能基础来研究界面上任何各向异性粒子之间的相互作用，我们正在将其应用于具有均匀接触角的圆柱形粒子。我们选择圆柱体作为第一种形状来研究，因为它们在界面上具有有趣的特性-它们在平面端面附近有高的界面面积密度，这有利于端到端的组装。我们现在详细地了解了界面上圆柱粒子之间的远场相互作用。然而，当颗粒靠近时，末端附近的强烈变形重叠，形成颗粒之间的强烈相互作用，称为“毛细管键”，其强度我们将用数字来量化。然后，我们将通过实验检查计算的有效性--这将建立在所有分离的界面上的圆柱体之间的相互作用。然后我们将解决三个组装目标，选择它们为开发定向粒子组装的领域铺平道路。我们将：i.在实验中确定，如标度所示，毛细相互作用对于亚微米到纳米级的颗粒是否重要，对于制造可退火结构和扩大毛细管组装的技术影响是否重要。使用磁性镊子表征毛细管组件的强度，这在利用颗粒稳定的乳剂、胶体和其他分级组件的应用中很重要。开发毛细识别元件，这种元件优先只与界面上的拼图一样的交配颗粒组装。这要求我们开发和了解毛细斥力，以赋予粒子相互作用的选择性。这些目标被选为新材料相关研究的种子，以开发各向异性颗粒组装。例如，有序取向的颗粒单分子膜可以用来外延生长新的3-D结构；定向、组装的各向异性颗粒可以开发出新的超材料类别；毛细管识别元件可以促进颗粒在设备内具有其他特征的注册，并可以用作传感器或读出。

Award: 1066284PI: StebeWe will perform fundamental studies to establish quantitative guiding principles for anisotropic capillary assembly, i.e. to relate particle shape, contact angle, and interface shape, to the range and strength of interactions and to the assemblies which form. To do so, we will study capillary assembly in experiment, numerics and theory. We have established an intellectual basis to study interactions between any anisotropic particles at interfaces which we are in the process of applying to cylindrically shaped particles with uniform contact angle. We choose cylinders as the first shape to study because they have intriguing properties when they are at interfaces- they have high interfacial area density near their planar end faces which cements end-to-end assembly. We now understand far field interactions between cylindrical particles at interfaces in detail. However, when the particles come close together, the strong deformations near the ends overlap, forming a strong interaction between particles termed a "capillary bond", whose strength we will quantify numerically. We will then check the validity of the calculation experimentally- this will establish the pair interactions between cylinders at interfaces at all separations. We will then address three assembly aims, selected to pave the way to fields which exploit oriented particle assemblies. We will: I. Establish in experiment whether, as scaling suggests, capillary interactions are important for sub-micron to nanoscale particles, important for making annealable structures and for extending the technological impact of capillary assembly. II. Characterize the strength of capillary assemblies using magnetic tweezers, important in applications that exploit particle-stabilized emulsions, colloidosomes, and other hierarchical assemblies. III. Develop capillary recognition elements, which would preferentially assemble only with mating particles like puzzle pieces on an interface. This requires that we develop and understand capillary repulsion to impart selectivity to particle interactions. These aims were selected to seed new materials-related research to exploit anisotropic particle assemblies. For example, ordered oriented particle monolayers could be exploited to epitaxially grow new 3-D structures; oriented, assembled anisotropic particles could allow new classes of metamaterials to be developed; capillary recognition elements could promote registry of particles with other features within devices, and could serve as sensors or read outs.