Collaborative Research: Fog Drop Reactions of Green Leaf Volatiles as a Source of Secondary Organic Aerosols

合作研究：绿叶挥发物作为二次有机气溶胶来源的雾滴反应

• 批准号: 1106569
• 负责人: Kalliat Valsaraj
• 金额: $ 39.36万
• 依托单位: Louisiana State University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2011
• 资助国家: 美国
• 起止时间: 2011-09-15 至 2015-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1106569&HistoricalAwards=false
• 关键词: Collaborative; Research; Fog; Drop; Reactions

Green leaf volatiles (GLVs) are potentially significant but of unknown importance as a source of aqueous-phase secondary organic aerosol (SOA). GLVs are reactive, oxygenated, organic compounds that are emitted from plants in significant quantities and that can react both at the surface of fog drops and within the bulk of the drops. These aqueous reactions can occur via photochemically generated oxidants such as hydroxyl radical, singlet molecular oxygen, and excited triplet states of organic compounds. GLVs are also oxidized in the gas phase to make more water soluble products that could also participate in fog-drop reactions to form SOA. The hypothesis driving this research is that the uptake and photooxidation of GLVs and their first generation oxidation products can be a significant source of secondary organic carbon in fogwater. This hypothesis will be tested through four objectives: (1) Collect and chemically characterize fogwaters from Louisiana and California. (2) Measure GLV photooxidation, changes in organic composition, and the formation of SOA in illuminated fogwaters. (3) Quantify photooxidants in the illuminated fog waters and their reactivity with GLVs. (4) Integrate results from each objective in order to determine the mechanisms for GLV reactions in fogwaters and assess the significance of GLVs as an aqueous source of SOA.A post-doctoral scholar, a graduate student, and undergraduate students will be mentored during the project, including through an LSU-UCD undergraduate exchange research program. The results from the research will be integrated into undergraduate and graduate teaching at both institutions. And, because fog events can affect the concentrations of regulated pollutants, especially PM2.5, in both Louisiana and California, results from this work will inform state air quality policy agencies.

绿叶挥发物（GLVs）作为水相二次有机气溶胶（SOA）的来源具有潜在的重要意义，但其重要性尚不清楚。glv是一种活性的、氧化的有机化合物，从植物中大量释放出来，可以在雾滴表面和雾滴内部发生反应。这些水反应可以通过光化学生成的氧化剂发生，如羟基自由基、单线态分子氧和有机化合物的激发态三重态。glv还在气相中被氧化，生成更多的水溶性产物，这些产物也可以参与雾滴反应，形成SOA。推动这项研究的假设是，glv的吸收和光氧化及其第一代氧化产物可能是雾水中二次有机碳的重要来源。这一假设将通过四个目标进行检验：(1)收集路易斯安那州和加利福尼亚州的雾水并对其进行化学表征。(2)测量光照雾水中GLV的光氧化、有机组成的变化和SOA的形成。(3)定量测定光照雾水中的光氧化剂及其与glv的反应性。(4)整合每个目标的结果，以确定雾水中GLV反应的机制，并评估GLV作为SOA水源的重要性。一名博士后学者、一名研究生和一名本科生将在项目期间接受指导，包括通过LSU-UCD本科生交流研究计划。研究结果将整合到两所大学的本科和研究生教学中。而且，由于在路易斯安那州和加利福尼亚州，雾事件会影响受管制污染物的浓度，尤其是PM2.5，因此这项工作的结果将为州空气质量政策机构提供信息。