AGS-PRF: Understanding the Early Growth of Atmospheric Nanoparticles

AGS-PRF：了解大气纳米粒子的早期生长

• 批准号: 1137757
• 负责人: Lea Hildebrandt Ruiz
• 金额: $ 8.6万
• 依托单位: Hildebrandt Lea
• 依托单位国家: 美国
• 项目类别: Fellowship Award
• 财政年份: 2011
• 资助国家: 美国
• 起止时间: 2011-08-01 至 2012-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1137757&HistoricalAwards=false
• 关键词: AGS; PRF; Understanding; Early; Growth

Dr. Lea Hildebrandt was awarded an Atmospheric and Geospace Sciences Postdoctoral Research Fellowship to conduct a research project at the National Center for Atmospheric Research in Boulder, Colorado and with colleagues at Portland State University and the University of Minnesota. Her project combines theoretical, laboratory and field measurements using newly developed instruments to explain chemical and physical processes affecting the growth rates of nanoparticles in the atmosphere. A main objective of the work is to understand the processes by which organic salts formed by reactions of organic acids (e.g., formic or acetic acid) and bases (e.g., methylamine, dimethylamine or trimethylamine) are taken up onto preexisting particles of known size. Seed particles 20-50 nanometers in size will be generated from sulfuric acid and ammonium salts, as well as from the nucleation of organic compounds. The effects of temperature, relative humidity, pH and organics will be varied to assess mechanisms of particle growth and the contribution of the amines and organic acids to this growth. Outdoor measurements will be taken in Boulder and at a rural site to learn about particle formation and growth under different conditions. The data will be used to develop and constrain models for nanoparticle growth rates.Nanoparticles range in size from about 1 to 10 nanometers. These atmospheric particles affect Earth's climate directly by scattering or absorbing solar radiation and indirectly by acting as seeds for water condensation and thereby influencing the formation and properties of clouds. Nanoparticles also affect human health by, for example, damaging respiratory and cardiovascular systems. The fundamental processes underlying new particle formation are not yet understood and consequently particle concentrations cannot be predicted reliably. The planned work will provide insights into the chemical and physical processes of atmospheric particle formation. Improved understanding of atmospheric particles will enable better prediction of cloud formation and development of better-informed policy actions concerning health effects.This project will also have education and training benefits because it supports the career development of a young scientist through mentorship, an opportunity to learn new techniques and skills, and development of a broader collegial network.

莱亚希尔德布兰特博士被授予大气和地球空间科学博士后研究奖学金，在科罗拉多博尔德的国家大气研究中心与波特兰州立大学和明尼苏达大学的同事一起进行研究项目。她的项目结合了理论，实验室和现场测量，使用新开发的仪器来解释影响大气中纳米颗粒生长速率的化学和物理过程。这项工作的一个主要目标是了解有机酸反应形成有机盐的过程（例如，甲酸或乙酸）和碱（例如，甲胺、二甲胺或三甲胺）被吸收到已知尺寸的预先存在的颗粒上。20-50纳米大小的种子颗粒将由硫酸和铵盐以及有机化合物的成核产生。温度、相对湿度、pH值和有机物的影响将变化，以评估颗粒生长的机制以及胺和有机酸对这种生长的贡献。室外测量将在博尔德和农村地区进行，以了解不同条件下颗粒的形成和生长。这些数据将被用于开发和约束纳米颗粒生长速率的模型。纳米颗粒的尺寸范围从大约1到10纳米。这些大气颗粒物通过散射或吸收太阳辐射直接影响地球气候，并通过充当水凝结的种子间接影响云的形成和性质。纳米颗粒还通过例如损害呼吸系统和心血管系统来影响人类健康。新粒子形成的基本过程尚未被理解，因此粒子浓度无法可靠地预测。计划中的工作将深入了解大气颗粒物形成的化学和物理过程。提高对大气颗粒物的认识将有助于更好地预测云的形成和制定更明智的健康影响政策行动，该项目还将产生教育和培训效益，因为它通过指导、学习新技术和技能的机会以及发展更广泛的大学网络，支持青年科学家的职业发展。

项目成果

Identification and quantification of particle growth channels during new particle formation

• DOI: 10.5194/acp-13-10215-2013
• 发表时间: 2013-04
• 期刊: Atmospheric Chemistry and Physics
• 影响因子: 6.3
• 作者: M. Pennington;B. Bzdek;J. DePalma;J. Smith;A. Kortelainen;L. H. Ruiz;T. Petäjä;M. Kulmala

Model for acid-base chemistry in nanoparticle growth (MABNAG)

• DOI: 10.5194/acp-13-12507-2013
• 发表时间: 2013-12
• 期刊: Atmospheric Chemistry and Physics
• 影响因子: 6.3
• 作者: T. Yli-Juuti;K. Barsanti;L. H. Ruiz;A. Kieloaho;U. Makkonen;T. Petäjä;T. Ruuskanen;M. Kulmala