RUI: Low Frequency Microwave Spectroscopy of van der Waals Complexes

RUI：范德华配合物的低频微波光谱

• 批准号: 1213560
• 负责人: Gordon Brown
• 金额: $ 14.42万
• 依托单位: Coker College
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2012
• 资助国家: 美国
• 起止时间: 2012-09-01 至 2016-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1213560&HistoricalAwards=false
• 关键词: RUI; Low; Frequency; Microwave; Spectroscopy

In this award, funded by the Chemical Measurement and Imaging Program of the Division of Chemistry, Professor Gordon Brown of Coker College and his undergraduate student researchers will be supported to study the intermolecular bonding in: (1) van der Waals complexes between carbon dioxide and nitrogen heterocycles and (2) complexes between halogen-containing small molecules and Lewis bases. The researchers will study these species with chirped-pulse Fourier transform microwave spectroscopy.Microwave spectroscopy is an important physical chemical method that gives precise information about molecular geometry and binding. The classes of species that Professor Brown and his students will study will provide information on potential carbon-capture/storage materials as well as fundamental information about the intermolecular interactions between halogen-containing species. The undergraduate students working on this project will gain useful experience in conducting physical chemical research with state-of-the-art equipment, and will be well-prepared for further study in the chemical sciences.

该奖项由化学系的化学测量和成像计划资助，将资助科克学院的戈登·布朗教授及其本科生研究人员研究以下两种分子间键合：（1）二氧化碳和氮杂环之间的货车德瓦尔斯络合物;以及（2）含卤素小分子和刘易斯碱之间的络合物。 研究人员将用啁啾脉冲傅里叶变换微波光谱学来研究这些物质。微波光谱学是一种重要的物理化学方法，可以提供有关分子几何形状和结合的精确信息。 布朗教授和他的学生将研究的物种类别将提供有关潜在的碳捕获/储存材料的信息，以及有关含卤素物种之间分子间相互作用的基本信息。 从事该项目的本科生将获得用最先进的设备进行物理化学研究的有益经验，并为进一步研究化学科学做好准备。