Thermal Interaction of Graphene with Metals

石墨烯与金属的热相互作用

• 批准号: 1236416
• 负责人: Satish Kumar
• 金额: $ 32.7万
• 依托单位: Georgia Tech Research Corporation
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2012
• 资助国家: 美国
• 起止时间: 2012-09-01 至 2016-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1236416&HistoricalAwards=false
• 关键词: Thermal; Interaction; Graphene; Metals

1236416KumarMany communication and military electronics require field - effect transistors which can operate in the frequency range of 100s of GHz to THz. Graphene is one of the thinnest and strongest known materials with exceptional electronic and thermal properties. The graphene based transistors can exceed the performance of existing transistors which makes them very attractive alternative for next generation high frequency devices. Graphene typically interacts with metals and insulators in its devices which significantly changes its properties. The performance of graphene based devices can be limited by the characteristics of the contact at the metal-graphene interface. It has become imperative to understand the electronic and thermal interaction between graphene and the metals it interfaces in its devices. The thermal and electrical transport across the metal-graphene interfaces is strongly dependent on the structure and nature of the chemical bond at the interface. It is important to decipher the coupled electronic-thermal transport at metal-graphene interfaces as a function of interfacial configuration in order to accurately model the performance of graphene devices and engineer the interfaces when possible. The objective of this research is to develop and employ systematic modeling and experimental techniques that consider the bonding and structure at metal-graphene interfaces in order to investigate the interfacial electrical-thermal transport and elucidate the crucial components of interfacial electrical/thermal contact resistances at time and length scales relevant to nanoscale graphene transistors. A first-principles-based study will be performed to correlate the interfacial thermal characteristics to the nature of chemical bonding and interfacial structure. Metal-graphene interface structures will be fabricated, characterized and thermal/electrical resistances will be measured. This research will lead to development of a new understanding of transport that sets the framework for modeling the performance of next-generation graphene devices with unprecedented accuracy, especially high-frequency and high-power devices. The understanding of interfacial transport at metal-graphene contact developed by this research will provide directions for efficient thermal management of graphene transistors which will allow them to operate in very high frequency regimes or operate the device at lower temperatures. Such achievement will significantly enhance the capabilities of graphene transistors and reduce a critical barrier for use of these devices in high frequency electronics applications while leading to a significant gain in the energy efficiency, performance, and operating life of future electronic systems. The project will lead to the development of educational materials in the area of Computational Modeling and Energy Transport for both graduate and undergraduate students. Small demonstrations and lectures prepared by this research will increase the awareness of K-12 students for energy related problems and also motivate them for college and graduate education.

Kumar许多通信和军事电子设备需要能够在100 GHz到THz的频率范围内工作的场效应晶体管。石墨烯是已知的最薄和最强的材料之一，具有优异的电子和热性能。基于石墨烯的晶体管可以超过现有晶体管的性能，这使得它们成为下一代高频器件的非常有吸引力的替代品。石墨烯通常与其器件中的金属和绝缘体相互作用，这会显着改变其特性。石墨烯基器件的性能可能受到金属-石墨烯界面处接触特性的限制。了解石墨烯与其设备中界面金属之间的电子和热相互作用已变得势在必行。金属-石墨烯界面的热传输和电传输强烈依赖于界面处化学键的结构和性质。重要的是要破译耦合的电子-热传输在金属-石墨烯界面作为界面配置的函数，以便准确地模拟石墨烯器件的性能，并在可能的情况下设计界面。本研究的目的是开发和采用系统的建模和实验技术，考虑在金属-石墨烯界面的键合和结构，以调查界面的电-热传输，并阐明界面的电/热接触电阻在时间和长度尺度相关的纳米级石墨烯晶体管的关键组成部分。将进行基于第一性原理的研究，以将界面热特性与化学键合和界面结构的性质相关联。金属-石墨烯界面结构将被制造，表征和热/电阻将被测量。这项研究将导致对运输的新理解的发展，为以前所未有的准确性建模下一代石墨烯设备的性能建立框架，特别是高频和高功率设备。 通过这项研究开发的金属-石墨烯接触处的界面传输的理解将为石墨烯晶体管的有效热管理提供方向，这将使它们能够在非常高的频率范围内工作或在较低的温度下工作。这一成就将显著增强石墨烯晶体管的能力，并降低这些器件在高频电子应用中使用的关键障碍，同时显著提高未来电子系统的能效、性能和工作寿命。该项目将为研究生和本科生编制计算建模和能源运输领域的教材。本研究准备的小型演示和讲座将提高K-12学生对能源相关问题的认识，并激励他们接受大学和研究生教育。