EAGER: Improving Ice Core Observations of Large Volcanic Eruptions, and Their Effect on Global Climate Change, with a Novel Sulfur Isotope Method

现代全球尺度变暖与太阳输出、温室气体以及自然(火山)和人为气溶胶之间的强迫作用之间的关系是一个具有挑战性的重要问题。到目前为止，大规模火山喷发的冷却效果是通过测量冰芯中的硫酸盐浓度来确定的。然而，只有将二氧化硫注入平流层的火山才能导致持续的全球降温，因为对流层中新的气溶胶的降雨非常有效。我们需要一种方法来区分在冰芯记录中有大量硫酸盐的火山，但没有平流层影响的火山(如圣海伦斯火山喷发)和那些到达平流层的火山，这样它们就可以在气候归属研究中脱离火山强迫作用。幸运的是，向平流层注入二氧化硫在产生的硫酸盐气溶胶的硫上留下了一个质量独立的同位素信号。这项研究由加州理工学院的一位教授领导，建立在一种在小样本上测量硫同位素的新技术的基础上，该技术将相关同位素系统的检测极限降低了三个数量级以上。这种新方法将被用来生成过去1000年来前100个火山事件的冰芯硫同位素变异性的时间序列。研究人员将确定哪些火山喷发实际上进入了平流层，从而导致了全球气候变冷。这些都是气候变暖归因研究中必须考虑的事件。这项研究将集中在格陵兰岛南部的冰芯上。将在南极冰芯中对某些事件进行交叉检查，以确认硫酸盐气溶胶的全球分布。这项工作的结果可能会改变我们对气候对二氧化碳增加的敏感性的理解。成果将为教育外展工作提供信息。资金也支持早期的职业科学家。

The attribution of modern planetary scale warming between forcings associated with solar output, greenhouse gases, and both natural (volcanic) and anthropogenic aerosols is a challenging and important problem. To date the cooling effect of large volcanic eruptions has been determined by measuring sulfate concentrations in ice cores. However, only volcanoes that inject sulfur dioxide into the stratosphere can cause sustained global cooling as the rain out of new aerosols in the troposphere is very efficient. We need a way to distinguish volcanoes with large amounts of sulfate in the ice core record, but no stratospheric impact (like the Mount St. Helens eruption), from those that reached the stratosphere, so that they can be taken out of the volcanic forcing function in climate attribution studies.Fortunately, injection of SO2 into the stratosphere leaves a mass independent isotopic signal on the sulfur of the resulting sulfate aerosols. This research, led by a professor at the California Institute of Technology, builds on a new technique for measuring sulfur isotopes on small samples that lowers the detection limit the relevant isotopic systems by over three orders of magnitude. This new method will be used to generate a time series of sulfur isotope variability in ice cores of the top 100 volcanic events of the last 1,000 years. The researchers will identify which volcanic eruptions actually entered the stratosphere and therefore caused a global climate cooling. These are the events that must be accounted for in climate warming attribution studies. The research will focus on an ice core from South Greenland. Certain events will be cross-checked in ice cores from Antarctic to confirm the global distribution of sulfate aerosol. The results of this work could be potentially transformative in changing our understanding of the sensitivity of climate to CO2 increases. Outcomes will inform educational outreach efforts. Funding also supports an early career scientist.