Collaborative Research: Battery Electrode Fabrication through Innovative Powder based Additive Manufacturing

合作研究：通过创新粉末增材制造制造电池电极

• 批准号: 1462343
• 负责人: Heng Pan
• 金额: $ 15万
• 依托单位: Missouri University of Science and Technology
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2015
• 资助国家: 美国
• 起止时间: 2015-04-01 至 2018-03-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1462343&HistoricalAwards=false
• 关键词: Collaborative; Research; Battery; Electrode; Fabrication

Lithium-ion batteries are one of the most widely used batteries due to their high energy density, long cycle life, and low self-discharge. With the rapid development of portable electronics, electrical vehicles, and grid systems, lithium-ion batteries will be more widely employed. However, current slurry based battery electrode manufacturing is costly, preventing wide applications of lithium-ion batteries. The organic solvent typically used in the slurry can be expensive. In addition, a time-consuming and energy-intensive drying procedure has to be employed. The evaporated solvent also needs to be recovered in order to prevent potential environmental pollution. Therefore, it is desirable to have solvent-free battery manufacturing processes. This award supports fundamental research to form the knowledge base for development of solvent-free battery manufacturing processes. Results from this research will enhance the U.S. competence in energy manufacturing industry and benefit the society by providing energy storage solutions. A major technical challenge in developing solvent-free battery manufacturing processes is to homogeneously disperse battery materials including active materials, conductive additives, and binder materials. This research aims to provide the new knowledge needed to overcome this challenge: (1) interfacial properties of the battery materials, (2) binder distribution characteristics during battery powder mixing, and (3) molten binder wettability and spreading kinetics on other materials during binder melting. The research team will perform multi-scale simulations (molecular dynamics at nanometer scale, finite difference modeling at micrometer scale, and discrete element modeling at micrometer to millimeter scales) to predict interfacial properties, binder spatial distribution after mixing, and molten binder spreading characteristics and surface coverages. Simulation results will be verified by surface energy measurements of dry powders and scanning electron microscopic observations of binder distributions after the powder mixing and binder melting steps respectively.

锂离子电池由于其高能量密度、长循环寿命和低自放电而成为最广泛使用的电池之一。随着便携式电子产品、电动汽车和电网系统的快速发展，锂离子电池将得到更广泛的应用。然而，目前基于浆料的电池电极制造成本高，阻碍了锂离子电池的广泛应用。通常用于浆料中的有机溶剂可能是昂贵的。此外，还必须采用耗时且耗能的干燥程序。蒸发的溶剂也需要回收，以防止潜在的环境污染。因此，期望具有无溶剂电池制造方法。该奖项支持基础研究，以形成无溶剂电池制造工艺开发的知识基础。这项研究的结果将提高美国在能源制造业的竞争力，并通过提供储能解决方案造福社会。开发无溶剂电池制造工艺的主要技术挑战是均匀分散电池材料，包括活性材料、导电添加剂和粘合剂材料。本研究旨在提供克服这一挑战所需的新知识：（1）电池材料的界面特性，（2）电池粉末混合过程中的粘合剂分布特性，以及（3）粘合剂熔融过程中熔融粘合剂的润湿性和在其他材料上的铺展动力学。研究团队将进行多尺度模拟（纳米尺度的分子动力学，微米尺度的有限差分建模，以及微米至毫米尺度的离散元建模），以预测界面特性，混合后的粘合剂空间分布，以及熔融粘合剂的扩散特性和表面覆盖率。模拟结果将分别通过粉末混合和粘结剂熔化步骤后干燥粉末的表面能测量和粘结剂分布的扫描电子显微镜观察来验证。