New Photophysical Processes in Impurity Doped Quantum Dots

非技术摘要掺杂半导体纳米结构在能量转换、能量存储、光催化、信息处理和信息存储技术中普遍存在，并且它们是包括基于自旋的电子学在内的许多未来器件技术的核心。在材料研究部固态和材料化学项目的支持下，该项目正在利用掺杂杂质的半导体产生纳米长度尺度的新物质。该项目还应用复杂的物理测量技术来阐明这些掺杂纳米晶体的技术相关物理特性。从该项目中获得的知识对每项技术都有广泛的影响。除了产生新的基础科学知识和新的物质形式外，该项目还为参与的本科生和研究生提供先进的技术培训，为他们未来在科学、工程和教育领域的职业做好准备。特别强调的是，通过本科生积极参与这项研究，将这项研究的实验和概念纳入华盛顿大学本科课程，接待本科院校的教职员工和学生作为华盛顿大学的访问科学家，以及在西雅图地区社区学院和高中开展成熟的外展活动，整合本科阶段的研究和教育。 技术摘要这项研究正在开发基于稀土和过渡金属掺杂半导体量子点的新型胶体发光纳米材料，该材料表现出前所未有的光物理和发光性能。与先进信息处理、成像、光谱转换和能量转换技术相关的磁光特性。正在应用整合合成、光谱、光物理和磁光方法的平衡研究工作，以对控制这些材料的物理性质的结构/功能关系有一个基本的了解。该项目的目标是全面了解掺杂量子点中的延迟发光和激子磁极化子现象，开发利用延迟发光探测量子点表面电子陷阱的新方法，阐明稀土掺杂量子点的磁光特性，以及将研究发现转化为可专利技术和教育工具。这项研究将产生新的基础科学见解，定义此类材料的制造和理解方式，并将加速基于此类材料的应用技术的出现，包括信息处理、光谱转换、成像和能量转换技术。

NON-TECHNICAL SUMMARYDoped semiconductor nanostructures are ubiquitous in energy conversion, energy storage, photocatalysis, information processing, and information storage technologies, and they are central to numerous futuristic device technologies including spin-based electronics. With support from the Solid State and Materials Chemistry program in the Division of Materials Research, this project is generating new forms of matter on nanometer length scales made from semiconductors doped with impurities. This project is also applying sophisticated physical measurement techniques to elucidate the technologically relevant physical properties of these doped nanocrystals. The knowledge gained from this project has broad implications for each of these technologies. In addition to yielding new fundamental scientific knowledge and new forms of matter, this project is also providing advanced technical training for participating undergraduate and graduate students to prepare them for future careers in science, engineering, and education. Special emphasis is being placed on integrating research and education at the undergraduate level through aggressive involvement of undergraduates in this research, incorporation of experiments and concepts from this research into the University of Washington undergraduate curriculum, hosting faculty and students from undergraduate institutions as visiting scientists at University of Washington, and mature outreach activities at Seattle-area community colleges and high schools.TECHNICAL SUMMARYThis research is developing new colloidal luminescent nanomaterials based on lanthanide- and transition-metal doped semiconductor quantum dots that show unprecedented photophysical and magneto-optical properties relevant to advanced information-processing, imaging, spectral conversion, and energy conversion technologies. A balanced research effort integrating synthetic, spectroscopic, photophysical, and magneto-optical methodologies is being applied to develop a fundamental understanding of the structure/function relationships that govern the physical properties of these materials. This project targets a thorough understanding of delayed luminescence and excitonic magnetic polaron phenomena in doped quantum dots, development of new methodologies for exploiting delayed luminescence to probe quantum dot surface electron traps, elucidation of the magneto-optical properties of lanthanide-doped quantum dots, and translation of research discoveries into patentable technologies and educational tools. This research will yield new fundamental scientific insights that will define the ways such materials are made and understood, and will accelerate the emergence of applied technologies based on such materials, including in information processing, spectral conversion, imaging, and energy conversion technologies.