SusChEM: Ionic Conduction Mechanisms in Low-cost and Rare-earth-free Fast Ion Conductors

SusChEM：低成本、无稀土快离子导体中的离子传导机制

• 批准号: 1508404
• 负责人: Yan-Yan Hu
• 金额: $ 29.76万
• 依托单位: Florida State University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2015
• 资助国家: 美国
• 起止时间: 2015-08-01 至 2020-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1508404&HistoricalAwards=false
• 关键词: SusChEM; Ionic; Conduction; Mechanisms; Low

Non-Technical AbstractFast ion conductors are an essential component of electrochemical devices such as fuel cells, solid-state batteries, gas separation membranes, and chemical sensors. An important criterion for ionic conductors to be suitable for such high-performance devices is high ionic conductivity at operating temperatures. In recent years, there has been a growing interest in developing sustainable, cost-effective, and high-conductivity oxide-ion conductors for intermediate-temperature solid-oxide fuel cells, one of the most efficient and cleanest energy conversion and storage technologies. One strategy is to design rare-earth-free fast-ion conductors. With support from the Solid State and Materials Chemistry Program in the Division of Materials Research at NSF, this project focuses on investigating the fundamental mechanisms of ionic conduction and revealing the relationship of chemical structure and conductivity in newly developed fast-ion conductors. The findings from this study provide valuable guidelines for rationally designing fast oxide-ion conductors. The research also develops unique characterization tools and protocols which are to be incorporated into the National High Magnetic Field Laboratory and made available to national and international users. Students assigned to this project, including undergraduates and a female minority graduate student, are provided with unique research training opportunities and guidance to advance their academic careers. The principal investigator's team disseminates the key findings and technological developments to the general public by creating educational videos and performing demonstrations at science events. Technical AbstractA new group of cost-effective and rare-earth-free fast ion conductors has been recently discovered. Some have unparalleled ion conductivity for intermediate-temperature solid-oxide fuel cells. The mechanism for such high ion conductivity is nevertheless unknown. This research uses Na-doped strontium silicates as model systems to understand how ions migrate in this class of fast-ion conductors. The study involves three major tasks including synthesis of strontium silicates with controlled alkaline element doping, advanced characterization with high-temperature high-resolution solid-state O-17, Na-23, and Si-29 NMR probing of structural defects and ion dynamics, and electrochemical measurements and computational efforts complementary to NMR characterizations to establish the important linkage between ion conductivity and structural defects.

非技术摘要快离子导体是电化学装置如燃料电池、固态电池、气体分离膜和化学传感器的重要组成部分。 离子导体适用于这种高性能器件的一个重要标准是在工作温度下的高离子电导率。 近年来，人们对开发用于中温固体氧化物燃料电池的可持续的、具有成本效益的和高电导率的氧化物离子导体的兴趣越来越大，中温固体氧化物燃料电池是最有效和最清洁的能量转换和存储技术之一。 一种策略是设计不含稀土的快离子导体。 在NSF材料研究部固态与材料化学计划的支持下，该项目侧重于研究离子传导的基本机制，并揭示新开发的快离子导体中化学结构与电导率的关系。 研究结果为合理设计氧化物快离子导体提供了有价值的指导。 该研究还开发了独特的表征工具和协议，这些工具和协议将被纳入国家高磁场实验室，并提供给国家和国际用户。 分配到这个项目的学生，包括本科生和一名少数民族女研究生，获得了独特的研究培训机会和指导，以促进他们的学术生涯。 首席研究员团队通过制作教育视频和在科学活动中进行演示，向公众传播关键发现和技术发展。 最近发现了一组新的具有成本效益且不含稀土的快离子导体。 其中一些具有无与伦比的离子传导性，可用于中温固体氧化物燃料电池。 然而，这种高离子传导率的机制尚不清楚。 本研究使用Na掺杂的硅酸锶作为模型系统，以了解离子如何在这类快离子导体中迁移。 该研究涉及三个主要任务，包括合成具有受控碱性元素掺杂的硅酸锶，使用高温高分辨率固态O-17，Na-23和Si-29 NMR探测结构缺陷和离子动力学的高级表征，以及电化学测量和计算工作补充NMR表征，以建立离子电导率和结构缺陷之间的重要联系。