Center for Sustainable Materials Chemistry

可持续材料化学中心

• 批准号: 1606982
• 负责人: Douglas Keszler
• 金额: $ 450万
• 依托单位: Oregon State University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2016
• 资助国家: 美国
• 起止时间: 2016-09-15 至 2020-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1606982&HistoricalAwards=false
• 关键词: Center; Sustainable; Materials; Chemistry

The Center for Sustainable Materials Chemistry (CSMC) develops new methods and techniques to advance the manufacturing of electronics and energy technologies. CSMC research synthesizes and characterizes thin films important in many technology areas including electronics, reflective coatings, and solar cells. CSMC designs these new chemical products in ways that minimize the use and generation of hazardous substances. Center researchers and partner companies commercialize products coming from this basic research. Students and trainees receive advanced research training as well as professional development to aid career success. Thin-layer metal oxides are important in many technology areas, including electronics, reflective coatings, and solar cells. The center has a broad set of goals: discover new methods to synthesize new and known metal oxo-hydroxide metal clusters and polyoxometalates as precursors to thin-layer metal oxides; determine the structures of these compounds in solution and in the solid state by combining diffraction, spectroscopic, and computational methods; understand the detailed chemical changes that occur as metal oxo-hydroxide clusters or polyoxometalates hydrolyze and condense to form intermediates and then dense metal oxides; and elucidate the elementary steps of photolytic and radiolytic-driven cluster condensation in films for nanopatterning. CSMC and its partners explore many possible applications of metal oxide thin films, including lithographic resists, photovoltaics, and electrical and optical devices. For graduate students and postdocs, CSMC integrates research training with professional development in the areas of innovation, entrepreneurship, team performance, leadership, project planning, and science communication.

可持续材料化学中心（CSMC）开发了推进电子和能源技术制造的新方法和技术。 CSMC研究综合并表征了许多技术领域中重要的薄膜，包括电子，反射涂料和太阳能电池。 CSMC以最大程度地减少和生成有害物质的方式设计了这些新化学产品。中心研究人员和合作伙伴公司将来自这项基础研究的产品商业化。学生和学员接受了高级研究培训以及专业发展，以帮助职业成功。薄层金属氧化物在许多技术领域都很重要，包括电子，反射涂料和太阳能电池。该中心具有广泛的目标：发现新的方法可以合成新的和已知的金属氧氧化物金属簇和多氧盐作为薄层金属氧化物的前体；通过结合衍射，光谱和计算方法，确定溶液和固态中这些化合物的结构。了解当金属氧羟氧化物簇或多氧盐水水解和凝结形成中间体，然后再形成密集的金属氧化物时发生的详细化学变化。并阐明了用于纳米图案的膜中光解和放射性驱动的簇凝结的基础步骤。 CSMC及其合作伙伴探索了金属氧化物薄膜的许多可能应用，包括光刻抗抑制作用，光伏以及电气和光学设备。对于研究生和博士后，CSMC将研究培训与创新，企业家精神，团队绩效，领导力，项目计划和科学传播领域的专业发展相结合。

项目成果

Enhanced NMR with Optical Pumping Yields 75 As Signals Selectively from a Buried GaAs Interface

采用光泵浦的增强型 NMR 可选择性地从掩埋 GaAs 界面产生 75 As 信号

• DOI: 10.1021/jacs.6b08970
• 发表时间: 2017
• 期刊: Journal of the American Chemical Society
• 影响因子: 15
• 作者: Willmering, Matthew M.;Ma, Zayd L.;Jenkins, Melanie A.;Conley, John F.;Hayes, Sophia E.
• 通讯作者: Hayes, Sophia E.

Impact of Relative Humidity during Spin-Deposition of Metal Oxide Thin Films from Aqueous Solution Precursors

• DOI: 10.1021/acs.chemmater.6b05200
• 发表时间: 2017-04-11
• 期刊: CHEMISTRY OF MATERIALS
• 影响因子: 8.6
• 作者: Plassmeyer, Paul N.;Mitchson, Gavin;Page, Catherine J.
• 通讯作者: Page, Catherine J.

Alkyltin Keggin Clusters Templated by Sodium

• DOI: 10.1002/anie.201701703
• 发表时间: 2017-08-14
• 期刊: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
• 影响因子: 16.6
• 作者: Saha, Sumit;Park, Deok-Hie;Nyman, May
• 通讯作者: Nyman, May

Same Precursor, Two Different Products: Comparing the Structural Evolution of In–Ga–O “Gel-Derived” Powders and Solution-Cast Films Using Pair Distribution Function Analysis

相同的前驱体，两种不同的产品：使用配对分布函数分析比较 In-Ga-O-凝胶衍生粉末和溶液流延薄膜的结构演变

• DOI: 10.1021/jacs.7b02097
• 发表时间: 2017
• 期刊: Journal of the American Chemical Society
• 影响因子: 15
• 作者: Wood, Suzannah R.;Woods, Keenan N.;Plassmeyer, Paul N.;Marsh, David A.;Johnson, Darren W.;Page, Catherine J.;Jensen, Kirsten M.;Johnson, David C.
• 通讯作者: Johnson, David C.