Revisiting the Dehydroannulenes

重新审视脱氢轮烯

• 批准号: 1609974
• 负责人: John Anthony
• 金额: $ 42.12万
• 依托单位: University of Kentucky Research Foundation
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2016
• 资助国家: 美国
• 起止时间: 2016-09-01 至 2021-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1609974&HistoricalAwards=false
• 关键词: Revisiting; Dehydroannulenes

The Macromolecular, Supramolecular and Nanochemistry Program of the Chemistry Division supports Professor John E. Anthony, Department of Chemistry, University of Kentucky. Professor Anthony and his research group are synthesizing and characterizing an unusual class of molecules called annulenes, which have carbon atoms arranged in a ring form. The molecules interact in solution to form aggregates and order in the solid state. Through this aggregation the molecules are able to communicate electronically and generate interesting optical properties. Such molecules could be applied to improving solar energy harvesting, enabling the construction of flexible color displays, and improving the sensitivity of sensors. The project is providing training to graduate and undergraduate researchers not only in the field of organic synthesis and characterization, but also in the use of new materials in electronic applications such as transistors. Professor Anthony is also partnering with the current Broadening Participation in Engineering program at the university to assist in recruiting students underrepresented in science to this project. Outreach activities involving high-school students are also being pursued. The field of organic electronics is built on traditional aromatic (or heteroaromatic) ring systems. As the field pushes toward higher-performance and multi-functional materials, traditional aromatic compounds are beginning to reach their limit. This project will explore dehydroannulenes, particularly formally anti-aromatic dehydro[12]annulenes, as potential components with highly exploitable properties. Key to this project is the effort to understand and control aggregation and solid-state order, as Professor Anthony's group has demonstrated with acenes. By exploiting key functionalization strategies, new molecules are being devised that exhibit ambipolar charge transport, minimized charge-carrier anisotropy, and understand how the nature of aggregation (in solution and solid state) impact singlet fission properties. Students involved in this project (graduate and undergrad researchers, as well as interns from a local high school) are performing the full range of tasks from material conception and design all the way to screening in electronic devices. In addition, a diverse group of students through NSF Broadening Participation in Engineering are being engaged in this research.

化学系的大分子，超分子和纳米化学计划支持教授约翰E。安东尼，肯塔基州大学化学系。 安东尼教授和他的研究小组正在合成和表征一类称为轮烯的不寻常分子，它们的碳原子排列成环状。 分子在溶液中相互作用形成聚集体，并在固态下有序化。 通过这种聚集，分子能够进行电子通信并产生有趣的光学特性。 这种分子可以用于改善太阳能收集，实现柔性彩色显示器的构建，并提高传感器的灵敏度。 该项目为研究生和本科生研究人员提供培训，不仅在有机合成和表征领域，而且在晶体管等电子应用中使用新材料方面。 安东尼教授还与该大学目前的扩大参与工程计划合作，以协助招募科学代表性不足的学生参加该项目。还开展了涉及高中生的外联活动。有机电子学领域是建立在传统的芳族（或杂芳族）环系统上的。随着该领域向更高性能和多功能材料的发展，传统的芳香族化合物开始达到极限。该项目将探索脱氢轮烯，特别是形式上的反芳香族环[12]轮烯，作为具有高度可开发特性的潜在组分。这个项目的关键是努力理解和控制聚集和固态秩序，安东尼教授的小组已经证明了与并苯。通过利用关键的功能化策略，正在设计新的分子，表现出双极电荷传输，最小化电荷载流子各向异性，并了解聚集的性质（在溶液和固态）如何影响单线态裂变性质。参与该项目的学生（研究生和本科生研究人员，以及当地高中的实习生）正在执行从材料概念和设计到电子设备筛选的全方位任务。此外，通过NSF扩大参与工程的不同群体的学生正在从事这项研究。