SBIR Phase II: Catalytic Conversion of Lignocellulosic Biomass into Furfural and Dissolving Pulp using Green Solvents

SBIR 第二阶段：使用绿色溶剂将木质纤维素生物质催化转化为糠醛和溶解浆

• 批准号: 1632394
• 负责人: David Alonso
• 金额: $ 74.94万
• 依托单位: Glucan Biorenewables LLC
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2016
• 资助国家: 美国
• 起止时间: 2016-09-15 至 2019-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1632394&HistoricalAwards=false
• 关键词: SBIR; Phase; II; Catalytic; Conversion

The broader impact/commercial potential of this Small Business Innovation Research Phase II project provides a technology platform to convert non-food biomass, such as wood and corn stalks, into biofuels, chemicals, and bioproducts. Biomass utilization is a solution to increase global sustainability and decrease petroleum-based greenhouse gas emissions. This project will use wood biomass to simultaneously co-produce three high-end products, dissolving pulp, furfural, and technical lignin, of which the dissolving pulp and furfural are the focus of this project. Current methods of producing these products only use one of the three primary biomass components. By co-producing two products, revenues increase and unit production costs decrease as production costs are spread over a larger product volume. The use of this solvent obtained from the biomass is a unique approach in the biomass conversion industry and offers an alternative to conventional enzyme or microbial processing. Benefits include restoring furfural production in the United States, decreasing dissolving pulp production costs, and increasing the commercial value of renewable biomass that currently has low or no value. This sustainable and environmentally friendly technology will increase global sustainability and revitalize rural economies by stimulating investment and creating jobs. The objectives of this Phase II research project are to demonstrate and advance to pilot scale our technology to simultaneously co-produce dissolving pulp and furfural from biomass using gamma valerolactone (GVL) as solvent. While other technologies focus on the production of a single product from biomass, GVL?' ability to fractionate lignocellulosic biomass into its three main components (cellulose, hemicellulose, and lignin) at high concentration and purity, produce significant cost and technical advantages. GVL fractionation produces solid cellulose at high yield (90%) and purity (90%), without the need for pre-treatment or further chemical refining. This cellulose can be converted into dissolving pulp for high-end applications such as textiles (rayon), cellophane, or microcrystalline cellulose. The hemicellulose fraction does not need to be separated from the GVL and is readily converted into furfural within GVL at high yields (75%) and high concentrations, minimizing separation costs. Preliminary mass and energy balances and techno-economic modeling based on lab data predict attractive financial returns. Tasks will focus on biomass fractionation to produce dissolving pulp, furfural purification, and GVL recovery at bench-scale. This experimental work will inform the engineering development for an integrated, continuous process, pilot demonstration unit.

这个小企业创新研究第二阶段项目的更广泛的影响/商业潜力提供了一个技术平台，将木材和玉米秸秆等非粮食生物质转化为生物燃料，化学品和生物产品。生物质利用是提高全球可持续性和减少石油基温室气体排放的一种解决方案。该项目将利用木材生物质同时联产溶解浆、糠醛和工业木质素三大高端产品，其中溶解浆和糠醛是该项目的重点。目前生产这些产品的方法仅使用三种主要生物质组分之一。通过共同生产两种产品，收入增加，单位生产成本降低，因为生产成本分散在更大的产品数量上。从生物质中获得的这种溶剂的使用是生物质转化工业中的独特方法，并且提供了常规酶或微生物处理的替代方案。其好处包括恢复美国的糠醛生产，降低溶解浆生产成本，以及增加目前价值低或没有价值的可再生生物质的商业价值。这种可持续和环保的技术将通过刺激投资和创造就业机会，提高全球可持续性，振兴农村经济。该第二阶段研究项目的目标是展示和推进我们的技术，以使用γ-戊内酯（GVL）作为溶剂，从生物质中同时联产溶解浆和糠醛。虽然其他技术侧重于从生物质生产单一产品，GVL？将木质纤维素生物质以高浓度和纯度破碎成其三种主要组分（纤维素、半纤维素和木质素）的能力产生显著的成本和技术优势。GVL分级法以高产率（90%）和纯度（90%）生产固体纤维素，而不需要预处理或进一步的化学精炼。这种纤维素可以转化为溶解纸浆，用于高端应用，如纺织品（人造丝），玻璃纸或微晶纤维素。半纤维素级分不需要从GVL中分离，并且在GVL中容易以高产率（75%）和高浓度转化为糠醛，从而使分离成本最小化。初步的质量和能量平衡以及基于实验室数据的技术经济模型预测了诱人的财务回报。任务将集中在生物质分馏，以生产溶解纸浆，糠醛纯化，并在实验室规模的GVL回收。这项实验工作将通知工程开发的综合，连续的过程，试点示范单位。