Bonding, charge transfer and aggregation of luminescent Pt-complexes at metallic interfaces (B13)

金属界面处发光 Pt 配合物的键合、电荷转移和聚集 (B13)

• 批准号: 225765956
• 金额: --
• 依托单位: Institute for Molecules and Materials
• 依托单位国家: 德国
• 项目类别: CRC/Transregios
• 财政年份: 2012
• 资助国家: 德国
• 起止时间: 2011-12-31 至 2016-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/225765956?language=en
• 关键词: Bonding; charge; transfer; aggregation; luminescent

Pt(II) complexes bearing tetradentate luminophores for vapor-deposited and solution-processed electroluminescent devices will be synthesized and investigated with the aid of density functional theory. They will be deposited onto metallic surfaces (single molecules, mono- and multilayers), and the feasibility of simplified devices consisting only of aggregated complexes at metallic substrates will be explored by electrically exciting them with an STM tip to spatially and spectrally photomap the luminescent species.

本论文将利用密度泛函理论合成并研究用于气相沉积和溶液处理电致发光器件的四齿铂配合物。它们将被沉积到金属表面（单分子，单层和多层），和简化的设备，仅由聚集的复合物在金属基板的可行性将探索通过电激发他们与STM尖端空间和光谱photomap的发光物种。