Intrinsic Properties of Zirconium Carbide Ceramics

碳化锆陶瓷的本质性能

• 批准号: 1742086
• 负责人: William Fahrenholtz
• 金额: $ 64万
• 依托单位: Missouri University of Science and Technology
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2017
• 资助国家: 美国
• 起止时间: 2017-08-01 至 2021-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1742086&HistoricalAwards=false
• 关键词: Intrinsic; Properties; Zirconium; Carbide; Ceramics

NON-TECHNICAL DESCRIPTION: This project focuses on the intrinsic mechanical, thermal, and electrical properties of zirconium carbide ceramics. Zirconium carbide is a candidate material for use in extreme environments such as those associated with hypersonic flight, nuclear fission, concentrated solar power, and high-speed machining. These applications involve extreme temperatures, heat fluxes, radiation levels, or other conditions that are beyond the capabilities of available materials today. Previous studies by other research groups have reported seemingly contradictory behavior for nominally identical zirconium carbide ceramics due to extrinsic effects such as carbon stoichiometry (e.g., the C:Zr ratio of the final ceramic) and the presence of impurities. Accordingly, the mechanical, thermal, and electrical properties are being investigated in a systematic and controlled manner. The project is using the unique experimental facilities at the Missouri University of Science and Technology, which include capabilities for producing dense ceramics with extremely high purity and characterizing properties from room temperature up to at least 2000°C. These studies are needed to provide data that can then be used to design zirconium carbide ceramics for use in extreme environments and enable revolutionary gains in performance and efficiency. This project is training two graduate students in the processing, densification, characterization, and analysis of materials for extreme environments, while also preparing them for careers in the aerospace and power-generation industries. Graduate students are mentoring undergraduates who are assigned research tasks and assist with outreach activities. The project team is also reaching out to teachers and students from rural high schools that lack access to research facilities needed for class projects. Groups of high school students are invited to use campus laboratories and the intent is to hire at least one high school student from those groups to work on the project during each summer.TECHNICAL DETAILS: The project is advancing the fundamental knowledge of the intrinsic properties of zirconium carbide ceramics with low (0.01 to 0.4 at%) hafnium contents and known oxygen and nitrogen impurity levels that are as low as possible. The four primary areas of emphasis are: 1) reactive synthesis of high purity zirconium carbide; 2) intrinsic properties of zirconium carbide; 3) ultra-high temperature microstructure- property relationships; and 4) effects of carbon stoichiometry, hafnium content, and other impurities on thermal transport. A focused experimental study is complemented by physics-based models to connect property measurements with fundamental electronic structure, bonding, and transport properties. The knowledge of zirconium carbide ceramics is being transformed by revealing intrinsic densification mechanisms, structure-property relationships at ultra-high temperatures, and the effects of carbon stoichiometry, oxygen content, and other impurity levels on properties. Graduate and undergraduate students working on this project are learning to design characterization methods and property tests for extreme environments that have heretofore not been explored through experimental methods, providing them with unique skills for future careers in fields such as aerospace, nuclear power, or alternative energy.

非技术描述：该项目的重点是碳化锆陶瓷的内在机械，热和电性能。碳化锆是用于极端环境的候选材料，例如与高超音速飞行，核裂变，集中太阳能和高速加工相关的环境。这些应用涉及极端温度、热通量、辐射水平或其他超出当今可用材料能力的条件。其他研究小组先前的研究已经报道了由于诸如碳化学计量（例如，最终陶瓷的C：Zr比）和杂质的存在。因此，机械，热和电气性能正在以系统和受控的方式进行研究。该项目使用了密苏里州科技大学独特的实验设施，其中包括生产具有极高纯度的致密陶瓷的能力，以及从室温到至少2000°C的特性。这些研究需要提供数据，然后可以用于设计用于极端环境的碳化锆陶瓷，并实现性能和效率的革命性提高。该项目正在培训两名研究生在极端环境下的材料加工，致密化，表征和分析，同时也为他们在航空航天和发电行业的职业生涯做好准备。研究生正在指导被分配研究任务的本科生，并协助开展外联活动。项目小组还接触到农村高中的教师和学生，他们无法获得课堂项目所需的研究设施。我们邀请高中生团体使用校园实验室，目的是在每个夏天从这些团体中雇用至少一名高中生参与该项目。该项目是推进低碳化锆陶瓷的固有特性的基础知识，（0.01至0.4原子%）的铪含量和尽可能低的已知氧和氮杂质水平。重点的四个主要领域是：1）高纯度碳化锆的反应合成; 2）碳化锆的固有性质; 3）超高温微观结构-性质关系;以及4）碳化学计量、铪含量和其它杂质对热传输的影响。一个重点实验研究是由物理为基础的模型，连接基本的电子结构，键合和传输特性的属性测量的补充。碳化锆陶瓷的知识正在通过揭示内在的致密化机制、超高温下的结构-性能关系以及碳化学计量比、氧含量和其他杂质水平对性能的影响而转变。从事该项目的研究生和本科生正在学习为迄今为止尚未通过实验方法探索的极端环境设计表征方法和性能测试，为他们在航空航天，核能或替代能源等领域的未来职业生涯提供独特的技能。

项目成果

Electronic structure and thermal conductivity of zirconium carbide with hafnium additions

• DOI: 10.1111/jace.17860
• 发表时间: 2021-05
• 期刊: Journal of the American Ceramic Society
• 影响因子: 3.9
• 作者: Yue Zhou;W. Fahrenholtz;J. Graham;G. Hilmas

Synthesis of ZrCx with controlled carbon stoichiometry by low temperature solid state reaction

• DOI: 10.1016/j.jeurceramsoc.2019.03.004
• 发表时间: 2019-07
• 期刊: Journal of the European Ceramic Society
• 影响因子: 5.7
• 作者: Yue Zhou;T. Heitmann;W. Fahrenholtz;G. Hilmas

From thermal conductive to thermal insulating: Effect of carbon vacancy content on lattice thermal conductivity of ZrC

• DOI: 10.1016/j.jmst.2020.11.068
• 发表时间: 2021-08
• 期刊: Journal of Materials Science & Technology
• 影响因子: 10.9
• 作者: Yue Zhou;W. Fahrenholtz;J. Graham;G. Hilmas

Carbon vacancy ordering in zirconium carbide powder

• DOI: 10.1111/jace.16964
• 发表时间: 2020-04
• 期刊: Journal of the American Ceramic Society
• 影响因子: 3.9
• 作者: Yue Zhou;T. Heitmann;E. Bohannan;Joseph C. Schaeperkoetter;W. Fahrenholtz;G. Hilmas

The irradiation response of ZrC ceramics under 10 MeV Au3+ ion irradiation at 800 ºC

• DOI: 10.1016/j.jeurceramsoc.2020.01.025
• 发表时间: 2020-05
• 期刊: Journal of The European Ceramic Society
• 影响因子: 5.7
• 作者: Raul Florez;M. Crespillo;Xiaoqing He;T. White;G. Hilmas;W. Fahrenholtz;J. Graham