An Experimental Investigation of the Synthesis of Complex Organic Molecules in Interstellar Analog Ices
An Experimental Investigation of the Synthesis of Complex Organic Molecules in Interstellar Analog Ices
批准号:
1800975
负责人:
Ralf Kaiser
金额:
$40.11万
依托单位:
依托单位国家:
美国
项目类别:
Continuing Grant
财政年份:
2018
资助国家:
美国
项目状态:
已结题
起止时间:
2018-09-01 至 2022-08-31
中文摘要
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英文摘要
This research project will investigate the formation of complex organic molecules (COMs) containing carbon, hydrogen, oxygen, and nitrogen atoms on interstellar ice analog samples that are held at ultra-high vacuum, low temperatures, and exposure to ionizing radiation --- laboratory conditions that simulate the environment of interstellar space. Results from the study will allow astronomers to understand how COMs are formed in interstellar clouds and the level of chemical complexity that can be built under the extreme conditions of interstellar space. This project will train graduate and undergraduate students, including ones from groups that are underrepresented in science, in advanced techniques of laboratory astrophysics research. The research team will also participate in training workshops for local high school teachers to help incorporate research activities into high school teaching.The research team will explore the synthesis of six key classes of COMs --- aldehydes, ketones, carboxylic acids, esters, amides, and isocyanates --- on interstellar ice analogs. They will do so by exposing interstellar ice analog samples to Lyman alpha radiation in an ultra-high vacuum space simulation chamber. The radiation energies and low temperatures in the chamber will approach those found in interstellar clouds, and the molecules produced in the experiment will be characterized in a highly complementary manner using mass spectrometry as well as infrared, Raman, and ultraviolet-visible spectroscopy. The project will support graduate and undergraduate students, and it will help expose high school classrooms to advanced research.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
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On the Formation of the Popcorn Flavorant 2,3‐Butanedione (CH 3 COCOCH 3 ) in Acetaldehyde‐Containing Interstellar Ices
爆米花香料2,3丁二酮(CH 3 COCOCH 3 )在乙醛星际冰中的形成
DOI:
10.1002/cphc.202000116
发表时间:
2020
期刊:
ChemPhysChem
影响因子:
2.9
作者:
[Kleimeier, N. Fabian, Turner, Andrew M., Fortenberry, Ryan C., Kaiser, Ralf I.]
通讯作者:
Kaiser, Ralf I.
An Experimental and Theoretical Investigation into the Formation of Ketene (H 2 CCO) and Ethynol (HCCOH) in Interstellar Analog Ices
星际模拟冰中乙烯酮 (H 2 CCO) 和乙醇 (HCCOH) 形成的实验和理论研究
DOI:
10.3847/1538-4357/ab8dbc
发表时间:
2020
期刊:
The Astrophysical Journal
影响因子:
--
作者:
[Turner, Andrew M., Koutsogiannis, Andreas S., Kleimeier, N. Fabian, Bergantini, Alexandre, Zhu, Cheng, Fortenberry, Ryan C., Kaiser, Ralf I.]
通讯作者:
Kaiser, Ralf I.
Rapid Radical–Radical Induced Explosive Desorption of Ice-coated Interstellar Nanoparticles
冰衣星际纳米粒子的快速自由基-自由基诱导爆炸解吸
DOI:
10.3847/1538-4357/ac116a
发表时间:
2021
期刊:
The Astrophysical Journal
影响因子:
--
作者:
[Zhu, Cheng, Bergantini, Alexandre, Singh, Santosh K., Abplanalp, Matthew J., Kaiser, Ralf I.]
通讯作者:
Kaiser, Ralf I.
Detection of 1 H -Triphosphirene ( c -HP 3 ) and 2-Triphosphenylidene (HP 3 ): The Isovalent Counterparts of 1 H -Triazirine ( c -HN 3 ) and Hydrazoic Acid (HN 3 )
1 H -三磷烯 ( c -HP 3 ) 和 2-三磷亚苯基 (HP 3 ) 的检测: 1 H -三嗪 ( c -HN 3 ) 和叠氮酸 (HN 3 ) 的等价对应物
DOI:
10.1021/acs.jpclett.2c00639
发表时间:
2022
期刊:
The Journal of Physical Chemistry Letters
影响因子:
--
作者:
[Zhang, Chaojiang, Zhu, Cheng, Eckhardt, André K., Kaiser, Ralf I.]
通讯作者:
Kaiser, Ralf I.
DOI:
10.1016/j.chempr.2020.10.003
发表时间:
2020-12-03
期刊:
CHEM
影响因子:
23.5
作者:
[Kleimeier, N. Fabian, Eckhardt, Andre K., Kaiser, Ralf, I]
通讯作者:
Kaiser, Ralf, I
共 16 条
Unraveling the Energetics and Dynamics of Atom-Radical and Radical-Radical Reactions of Atomic Silicon and Silylidyne Radicals with Main Group Hydride Radicals
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批准号:2244717
-
项目类别:Standard Grant
-
资助金额:$52.0万
-
财政年份:2023
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负责人:Ralf Kaiser
-
依托单位:
MoMIS - Mobile Muon Imaging System
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批准号:ST/V002260/1
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项目类别:Research Grant
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资助金额:$42.52万
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财政年份:2021
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负责人:Ralf Kaiser
-
依托单位:
An Experimental Investigation of the Formation of Complex Organic Molecules in Interstellar Analog Ices
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批准号:2103269
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项目类别:Standard Grant
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资助金额:$42.07万
-
财政年份:2021
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负责人:Ralf Kaiser
-
依托单位:
Untangling the Energetics and Dynamics of Reactions of Ground State Silylidyne Radicals with Mononuclear Main Group Hydrides
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批准号:1853541
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项目类别:Standard Grant
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资助金额:$52.0万
-
财政年份:2019
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负责人:Ralf Kaiser
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依托单位:
An Experimental Investigation of the Synthesis of Complex Organic Molecules in Interstellar Analog Ices
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批准号:1505502
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项目类别:Standard Grant
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资助金额:$33.9万
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财政年份:2015
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负责人:Ralf Kaiser
-
依托单位:
Untangling the Energetics and Dynamics of Reactions of Ground State Silylidyne Radicals with Hydrocarbon Molecules
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批准号:1360658
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项目类别:Standard Grant
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资助金额:$48.0万
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财政年份:2014
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负责人:Ralf Kaiser
-
依托单位:
Untangling the Energetics and Dynamics of Reactions of Ground State Silicon Atoms with Small Hydrocarbon Radicals
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批准号:0948258
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项目类别:Continuing Grant
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资助金额:$43.2万
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财政年份:2010
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负责人:Ralf Kaiser
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依托单位:
CRC: Chemistry of Unsaturated Hydrocarbons in Titan's Atmosphere
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批准号:0627854
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项目类别:Continuing Grant
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资助金额:$236.7万
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财政年份:2006
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负责人:Ralf Kaiser
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依托单位:
CAREER: Untangling the Energetics and Dynamics of Atom-Radical and Radical-Radical Reactions
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批准号:0234461
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项目类别:Standard Grant
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资助金额:$59.94万
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财政年份:2003
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负责人:Ralf Kaiser
-
依托单位:
海外基金