GOALI/Collaborative Research: Roll-to-Roll Atomic Layer Deposition of Selenium-based Battery Cathodes

GOALI/合作研究：硒基电池阴极的卷对卷原子层沉积

• 批准号: 1911900
• 负责人: Dibakar Datta
• 金额: $ 19.46万
• 依托单位: New Jersey Institute of Technology
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2019
• 资助国家: 美国
• 起止时间: 2019-09-01 至 2023-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1911900&HistoricalAwards=false
• 关键词: GOALI; Collaborative; Research; Roll; Atomic

This Grant Opportunities for Academic Liaison with Industry (GOALI) award supports fundamental scientific research across multiple length-scales ranging from atomic to macro-scale for manufacturing of industrial-scale selenium-based battery electrodes. The most commonly used lithium-ion batteries are not sufficient to meet the ever-increasing energy demand of our society. Lithium-selenium batteries are a viable replacement for lithium-ion batteries. However, the lack of basic knowledge that controls the processing-structure-performance relations is hindering the progress of manufacturing lithium-selenium batteries at industrial scale. This project addresses these issues and creates transformative new insights into roll-to-roll atomic layer deposition, which is a novel and largely unexplored manufacturing process for selenium battery electrode manufacturing. The roll-to-roll technology is an important manufacturing platform for mass-production of many film-type products. It is seen as a potential 'game-changer' for the U.S. economy. Atomic layer deposition is a layer-by-layer process that results in the deposition of thin films one atomic layer at a time. This research enables broad penetration of high-power batteries into applications where conventional batteries are not suitable, leading to major energy savings and carbon dioxide reduction. The GOALI partnership facilitates in translating laboratory knowledge into manufacturing technology and provides an opportunity for students to combine academic experience with industrial research and development. The award provides opportunities for U.S. Military Veterans, elementary to high-school students, and STEM teachers to engage in activities in both academic and industrial settings. Lithium-selenium batteries have the potential to store twice the energy as state-of-the-art lithium-ion batteries and potentially be employed for high power applications. This research elucidates key aspects that control the processing-structure-performance relations in nanolayered selenium-based electrodes manufactured by roll-to-roll (R2R) atomic layer deposition (ALD). The computational plan focuses on molecular dynamics (MD), density functional theory (DFT), DFT with finite element solvers (DFT-FE), and ab initio molecular dynamics (AIMD) simulations for electrode development. The experimental plan focuses on the study of industrial-scale R2R modeled on laboratory-scale R2R, electrochemical analysis, and analytical characterization of ALD coating/Se/2D carbon electrode (cathode) architectures. The GOALI partner is involved in translating the laboratory ALD results into R2R ALD small-scale manufacturing runs and packaging the materials into commercial-scale pouch cells. The effort combines state-of-the-art pilot-line R2R manufacturing of both electrodes and the ALD coatings with advanced microstructural characterization employing techniques such as TEM and surface science XPS. Electroanalytical testing of electrodes is performed at multiscale, from laboratory 2032 (22 mm diameter x 3.2 mm height) button cells to commercial pouch cells. The academia-industry partnership that is at the core of this research brings a unique intellectual advantage to the approach, allowing a broad spectrum of learning starting at fundamental mechanistic insight to fabricating industrial-scale electrodes.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

这一学术联系机会奖(GOALI)支持从原子到宏观多个长度尺度的基础科学研究，用于制造工业规模的硒电池电极。最常用的锂离子电池不足以满足我们社会日益增长的能源需求。锂硒电池是锂离子电池的可行替代品。然而，缺乏控制加工-结构-性能关系的基础知识阻碍了锂硒电池的工业化生产。该项目解决了这些问题，并对卷对卷原子层沉积产生了革命性的新见解，这是一种用于制造硒电池电极的新的、基本上未被探索的制造工艺。卷对卷技术是许多薄膜类产品批量生产的重要制造平台。它被视为美国经济潜在的“游戏规则改变者”。原子层沉积是一种逐层沉积薄膜的过程，每次沉积一个原子层。这项研究使高功率电池能够广泛渗透到传统电池不适合的应用中，从而大大节省能源和减少二氧化碳。GOALI伙伴关系有助于将实验室知识转化为制造技术，并为学生提供将学术经验与工业研究和开发相结合的机会。该奖项为美国退伍军人、小学到高中生以及STEM教师提供了在学术和工业环境中从事活动的机会。锂硒电池具有比最先进的锂离子电池储存两倍的能量的潜力，并有可能用于高功率应用。这项研究阐明了控制卷对卷(R2R)原子层沉积(ALD)制备的纳米层硒电极的工艺-结构-性能关系的关键因素。计算计划侧重于分子动力学(MD)、密度泛函理论(DFT)、有限元解的密度泛函理论(DFT-FE)和从头算分子动力学(AIMD)模拟电极的发展。该实验计划的重点是以实验室规模的R2R为模型进行工业规模的R2R的研究，电化学分析，以及ALD涂层/Se/2D碳电极(阴极)结构的分析表征。Goali合作伙伴参与将实验室ALD结果转化为R2R ALD小规模生产，并将材料包装成商业规模的袋状细胞。这项工作将电极和ALD涂层的最先进中试生产线R2R制造与先进的微结构表征相结合，采用了透射电子显微镜和表面科学XPS等技术。电极的电分析测试是在多个尺度上进行的，从实验室2032(直径22 mm x 3.2 mm高)纽扣电池到商业储袋电池。作为这项研究的核心，学术界和产业界的合作伙伴关系为这种方法带来了独特的智力优势，允许从基本机械洞察到制造工业规模的电极的广泛学习。这一奖项反映了NSF的法定使命，并通过使用基金会的智力优势和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Selenium infiltrated hierarchical hollow carbon spheres display rapid kinetics and extended cycling as lithium metal battery (LMB) cathodes

• DOI: 10.1039/d1ta04705a
• 发表时间: 2021-08
• 期刊: Journal of Materials Chemistry A
• 影响因子: 11.9
• 作者: Yixian Wang;Hongchang Hao;Sooyeon Hwang;Pengcheng Liu;Yixin Xu;J. Boscoboinik;D. Datta;D. Mitlin-D.-Mi

Effects of Graphene Interface on Potassiation in a Graphene–Selenium Heterostructure Cathode for Potassium-Ion Batteries

• DOI: 10.1021/acsaem.3c00989
• 发表时间: 2023-04
• 期刊: ACS Applied Energy Materials
• 影响因子: 6.4
• 作者: Vidushi Sharma;D. Datta