Manufacturing of High-Performance Lithium-Sulfur Batteries Using Microbial Nanomachines

该项目为制造高性能锂硫电池的微生物纳米机械制造工艺提供了新的知识。这种潜在的可扩展和环境友好的过程的新奇之处在于使用微生物纳米机器来清除环境污染物来生产纳米材料。该奖项支持研究硫化物氧化菌和纤维素菌，以分别生产用于高性能锂硫电池的含硫纳米颗粒和纳米纤维素膜。含硫纳米颗粒是由硫化物氧化细菌通过收集环境或工业硫化物污染物而产生的。纳米纤维素膜是由纤维素细菌通过回收某些农业或工业副产品/废物来制造的。这项研究的结果将极大地影响未来的高性能电池技术，使美国经济和社会受益。这一融合研究涉及生物化学、材料科学和电化学。它的多学科方法培训未来的先进制造业劳动力，促进妇女和代表不足的群体的参与，并对STEM教育产生积极影响。发展高性能锂硫电池必须解决可溶性锂多硫化物穿梭等问题。这需要生产硫磺阴极纳米结构的制造工艺，这种纳米结构可以物理捕获和化学结合这些多硫化物，以及作为关闭穿梭路径的第二个屏障的功能化电池隔膜。在自然界中，硫化物氧化菌可以将硫化物污染物氧化成元素硫纳米颗粒，并将其储存在体内。也有细菌通过收获农业副产品来产生高质量的纳米纤维素膜，适合用作电池隔膜。该项目研究了两种工艺：一种是培养硫化物氧化细菌以生产用于硫阴极的含硫纳米颗粒，另一种是细菌纤维素发酵工艺及其离子修饰作为电池隔膜。当这些组件组合在一起时，它们协同工作，解决了锂硫电池技术面临的多硫化物穿梭和其他问题。研究内容包括多硫化物穿梭阻燃机理研究、工艺开发、纳米结构控制与剪裁、材料表征、电池性能测试等。他们共同推动了对通过使用微生物纳米机器制造高性能锂硫电池的可扩展纳米制造过程来产生合理设计的纳米结构的理解。这一奖项反映了NSF的法定使命，并通过使用基金会的智力优势和更广泛的影响审查标准进行评估，被认为值得支持。

This project contributes new knowledge related to a microbial nanomachine-based manufacturing process for fabricating high-performance lithium-sulfur batteries. The novelty of this potentially-scalable and environmentally-friendly process is the use of microbial nanomachines that scavenge environmental pollutants to produce nanoscale materials. This award supports research to investigate sulfide oxidizing bacteria and cellulose bacteria to produce sulfur-containing nanoparticles and nanocellulose membranes, respectively, for use in high-performance lithium-sulfur batteries. The sulfur-containing nanoparticles are produced by sulfide oxidizing bacteria by harvesting environmental or industrial sulfide pollutants. The nanocellulose membrane is manufactured by cellulose bacteria through recycling certain agriculture or industry byproducts/wastes. The outcome of this research greatly impacts future high-performance battery technology, which benefits the U.S. economy and society. This convergent research involves biochemistry, material science and electrochemistry. Its multi-disciplinary approach trains the future advanced manufacturing workforce, fosters participation of women and underrepresented groups, and positively impacts STEM education. The challenge of soluble lithium polysulfides shuttling and other problems must be solved to develop high-performance lithium-sulfur batteries. This calls for manufacturing processes that produce a sulfur cathode nanostructure, which can physically trap and chemically bind these polysulfides, and a functionalized battery separator as a second barrier to close off the shuttling path. In nature, sulfide oxidizing bacteria can oxidize sulfide pollutants into elemental sulfur nanoparticles and store them in their bodies. There are also bacteria which produce high-quality nanocellulose membranes suitable as a battery separator by harvesting agriculture byproducts. This project studies two processes; a sulfide oxidizing bacteria cultured to produce sulfur-containing nanoparticles used in sulfur cathodes and a bacterial cellulose fermentation process along with its ionic modification as the battery separator. When combined, these components work cooperatively in solving the polysulfides shuttling and other problems faced by the lithium-sulfur battery technology. The research involves the study of polysulfides shuttling retardation mechanism, process development, nanostructure control and tailoring, material characterization, and battery performance testing. Together they advance the understanding of generating rationally-designed nanostructures via the scalable nanomanufacturing process using microbial nanomachines to manufacture high-performance lithium-sulfur batteries.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.