Heterogeneous and Multiphase Reactions of Volatile and Semi-Volatile Organic Compounds on Mineral Dust Aerosol
挥发性和半挥发性有机化合物在矿尘气溶胶上的非均相和多相反应
基本信息
- 批准号:2002607
- 负责人:
- 金额:$ 56.18万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Standard Grant
- 财政年份:2020
- 资助国家:美国
- 起止时间:2020-07-15 至 2024-06-30
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
This award from the Environmental Chemical Sciences Program in the NSF Division of Chemistry supports Professor Vicky Grassian at the University of California, San Diego. Professor Grassian and her team investigate the role of aerosols, in particular, their interactions with different gases in the atmosphere from both natural and pollution sources. Aerosols are solid or liquid particles suspended in air. They are an important component of the Earth’s atmosphere and can impact human health and climate. This project investigates the chemical reactions of mineral dust aerosols, a class of aerosols from windblown soils and desert regions that circulate around the globe. Understanding the interaction of mineral dust aerosol with gases increases our knowledge of the different components that make up the atmosphere and the air we breathe. Other broader impacts include the training of undergraduate and graduate students. Professor Grassian has a research program that attracts a large and diverse number of students including many women and underrepresented minorities. Additionally, educational and outreach activities for the broader public will be developed. Dr. Grassian leads efforts to expand and enhance the effectiveness of outreach activities including further development of hands-on activities for the broader public that span K-12 students including activities that relate increase in volatile organic emissions to familiar consumer products.,This project focuses on laboratory studies of reactions of volatile and semi-volatile organic compounds with mineral dust aerosol, an important component of the Earth’s atmosphere. The organic compounds include trace atmospheric gases termed volatile chemical products (VCPs), which recently have been identified as a class of compounds that comes predominantly from industrial sources. A multi-technique, molecule-based approach employing mass spectrometry and vibrational spectroscopy is used to probe mechanistic details of surface adsorption and subsequent reactions of the adsorbed organic compounds with acidic gases and oxidants. The research project identifies how mechanisms for these reactions change as a function of relative humidity and the presence of adsorbed water. The project also determines how the different components of mineral dust aerosol impact its reactivity. New products formed in these reactions are being characterized. This research aims to provide new insights and a better understanding of the heterogeneous and multiphase chemistry of volatile and semi-volatile organic compounds with mineral dust aerosols from the perspective of fundamental molecular processes as well as potential global impacts.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
这一奖项来自美国国家科学基金会化学部的环境化学科学项目,支持加州大学圣地亚哥分校的Vicky Grassian教授。格拉西安教授和她的团队研究了气溶胶的作用,特别是它们与大气中来自自然和污染源的不同气体的相互作用。气溶胶是悬浮在空气中的固体或液体颗粒。它们是地球大气的重要组成部分,会影响人类健康和气候。这个项目研究矿物粉尘气溶胶的化学反应,矿物粉尘气溶胶是一种来自风化土壤和沙漠地区的气溶胶,在全球范围内循环。了解矿物粉尘气溶胶与气体的相互作用增加了我们对构成大气和我们呼吸的空气的不同成分的了解。其他更广泛的影响包括本科生和研究生的培训。格拉西安教授有一个研究项目,吸引了大量多样化的学生,包括许多女性和代表性较低的少数族裔。此外,还将为更广泛的公众开展教育和外联活动。Grassian博士领导了扩大和提高外联活动有效性的努力,包括进一步为更广泛的公众开发涵盖K-12学生的动手活动,包括将挥发性有机化合物排放的增加与熟悉的消费品联系起来的活动。该项目侧重于实验室研究挥发性和半挥发性有机化合物与地球大气的重要组成部分矿物粉尘气溶胶的反应。有机化合物包括被称为挥发性化学产品(VCP)的微量大气气体,最近被确认为一类主要来自工业来源的化合物。利用质谱学和振动光谱学的多技术、基于分子的方法来探索吸附的有机化合物的表面吸附以及随后与酸性气体和氧化剂的反应的机理细节。该研究项目确定了这些反应的机制如何随着相对湿度和吸附水的存在而变化。该项目还确定了矿物粉尘气溶胶的不同成分如何影响其反应性。在这些反应中形成的新产品正在进行表征。这项研究旨在从基本分子过程和潜在的全球影响的角度对挥发性和半挥发性有机化合物与矿物粉尘气溶胶的异相和多相化学提供新的见解和更好的理解。该奖项反映了NSF的法定使命,并通过使用基金会的智力优势和更广泛的影响审查标准进行评估,被认为值得支持。
项目成果
期刊论文数量(3)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
Heterogeneous chemistry of methyl ethyl ketone on mineral oxide surfaces: impacts of relative humidity and nitrogen dioxide on product formation
- DOI:10.1039/d3ea00023k
- 发表时间:2023
- 期刊:
- 影响因子:0
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Vicki Grassian其他文献
Vicki Grassian的其他文献
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{{ truncateString('Vicki Grassian', 18)}}的其他基金
Collaborative Research: Sulfur Oxide Chemistry in Aqueous Aerosols--Mechanisms and Kinetics of Inorganic Sulfate and Organosulfur Compound Formation in the Atmosphere
合作研究:水气溶胶中的硫氧化物化学--大气中无机硫酸盐和有机硫化合物形成的机理和动力学
- 批准号:
2302301 - 财政年份:2023
- 资助金额:
$ 56.18万 - 项目类别:
Standard Grant
A Laboratory Study to Investigate Inorganic and Organic Sulfate Formation in Multiphase Processes Involving Mineral Dust and Other Metal-Containing Aerosols
研究涉及矿物粉尘和其他含金属气溶胶的多相过程中无机和有机硫酸盐形成的实验室研究
- 批准号:
1702488 - 财政年份:2017
- 资助金额:
$ 56.18万 - 项目类别:
Standard Grant
Molecular-Based Studies of Metal, Metal Oxide and Metal Sulfide Nanoparticle Transformations in the Environment
环境中金属、金属氧化物和金属硫化物纳米粒子转化的分子研究
- 批准号:
1606607 - 财政年份:2016
- 资助金额:
$ 56.18万 - 项目类别:
Standard Grant
EAGER: NanoEHS Critical Needs - Determining Surface Composition in Biological Media and the Roles of Core Composition and Very Small Particles
EAGER:NanoEHS 关键需求 - 确定生物介质中的表面成分以及核心成分和非常小的颗粒的作用
- 批准号:
1640936 - 财政年份:2016
- 资助金额:
$ 56.18万 - 项目类别:
Standard Grant
Heterogeneous Chemistry and Photochemistry in the Troposphere: Reactions of Mineral Dust and Other Metal-Containing Particle Surfaces at the Gas-Solid and Liquid-Solid Interface
对流层中的非均相化学和光化学:矿尘和其他含金属颗粒表面在气-固和液-固界面的反应
- 批准号:
1639757 - 财政年份:2016
- 资助金额:
$ 56.18万 - 项目类别:
Continuing Grant
NanoEHS: A Workshop Focused on Fundamental Science Needs, November 1, 2014, Boston, MA
NanoEHS:专注于基础科学需求的研讨会,2014 年 11 月 1 日,马萨诸塞州波士顿
- 批准号:
1657679 - 财政年份:2016
- 资助金额:
$ 56.18万 - 项目类别:
Standard Grant
EAGER: NanoEHS Critical Needs - Determining Surface Composition in Biological Media and the Roles of Core Composition and Very Small Particles
EAGER:NanoEHS 关键需求 - 确定生物介质中的表面成分以及核心成分和非常小的颗粒的作用
- 批准号:
1424502 - 财政年份:2014
- 资助金额:
$ 56.18万 - 项目类别:
Standard Grant
NanoEHS: A Workshop Focused on Fundamental Science Needs, November 1, 2014, Boston, MA
NanoEHS:专注于基础科学需求的研讨会,2014 年 11 月 1 日,马萨诸塞州波士顿
- 批准号:
1441457 - 财政年份:2014
- 资助金额:
$ 56.18万 - 项目类别:
Standard Grant
Heterogeneous Chemistry and Photochemistry in the Troposphere: Reactions of Mineral Dust and Other Metal-Containing Particle Surfaces at the Gas-Solid and Liquid-Solid Interface
对流层中的非均相化学和光化学:矿尘和其他含金属颗粒表面在气-固和液-固界面的反应
- 批准号:
1305723 - 财政年份:2013
- 资助金额:
$ 56.18万 - 项目类别:
Continuing Grant
Chemistry Workshop on Nanomaterials and the Environment
纳米材料与环境化学研讨会
- 批准号:
1138118 - 财政年份:2011
- 资助金额:
$ 56.18万 - 项目类别:
Standard Grant
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大气还原氮的光氧化和多相反应
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