Rational Design of Oxide Cathode Coatings for High Performance Li-ion Batteries

锂离子电池（LIBs）无处不在，被用作便携式电子产品和电动汽车的能量存储设备。提高这些电池的能量密度对于延长手机的运行时间和增加电动汽车的行驶里程是必要的。提高锂离子电池能量密度的关键是实现当前锂离子电池阴极的高压充电。由于阴极和电解液之间的寄生反应，在充放电循环过程中，容量会迅速衰减，这也会破坏电池的安全性。克服这一问题的一个有效策略是在阴极表面涂上一层化学惰性材料，作为防止寄生反应发生的屏障。该项目的目标是了解表面涂层的功能，以实现高能量密度锂离子电池的高压阴极。这项研究将解决lib进展中的一个重大挑战。为了扩大STEM的参与，我们将推行艺术与科学的伙伴关系，将科学进步与现实应用联系起来。这将在宾厄姆顿大学现有的第一年沉浸式研究和美国国家科学基金会本科生研究经验项目中实施。这项研究也将提供劳动力培训机会，让学生熟练掌握制造级电池组装。商业化的锂离子电池技术依赖于富镍层状氧化物阴极，以实现当今应用（电动汽车、电网存储等）所需的高能量密度和功率输出。涂层已被广泛用于改善这些氧化物阴极的性能和可靠性的工程解决方案，但其在循环过程中的潜在功能尚不清楚。本项目研究氧化铝涂层（Al2O3和LiAlO2）及其对两种体系（高质量LiCoO2薄膜和商用LiNi0.8Mn0.1Co0.1O2 （NMC 811）微米级颗粒）锂离子传输、阴极-电解质界面稳定性和循环性能的影响。原子和化学x射线光谱和衍射表征将与从头算分子动力学模拟相连接，以直接确定使用铝涂层可以避免有害降解途径的程度，例如颗粒破裂，氧气损失和过渡金属还原。该研究将提供对原子水平过程的深入了解，以指导可扩展到制造级测试的坚固涂层的开发。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

Li-ion batteries (LIBs) are ubiquitous, used as energy storage devices in portable electronics and electrical vehicles. Increasing the energy density of these batteries is necessary to allow for longer runtime of cell phones and the increased range of electrical vehicles. Critical to increasing the energy density of LIBs is enabling high-voltage charging of current LIB cathodes. This effort is hindered by the rapid capacity fading over charge-discharge cycles caused by parasitic reactions between the cathode and the electrolyte that also undermine the battery’s safety. One effective strategy to overcome this problem is to coat the cathode surface with a chemically inert material as a barrier to prevent the parasitic reactions from occurring. The goal of this project is to understand the functionality of the surface coating to enable high-voltage cathodes for high energy density LIBs. This research will address a major challenge in the advancement of LIBs. To broaden the participation in STEM, an art-science partnership will be implemented to connect scientific advances to real-world applications. This will be implemented in the existing First-year Research Immersion and the NSF Research Experience for Undergraduates programs at Binghamton University. This research will also offer workforce training opportunities for students to gain proficiency in manufacturing-level battery assembly. Commercialized Li-ion battery technologies are reliant on Ni-rich layered oxide cathodes to achieve the high energy density and power output required for today’s applications (electric vehicles, grid storage, etc.). Coating layers have been widely employed as engineering solutions to improve the performance and reliability of these oxide cathodes, yet their underlying functionality during cycling remains unclear. This project addresses aluminum oxide coatings (Al2O3 and LiAlO2) and their impact on Li-ion transport, cathode-electrolyte interface stability, and cycling performance for two systems: high quality LiCoO2 thin films and commercial LiNi0.8Mn0.1Co0.1O2 (NMC 811) micron-sized particles. Atomic and chemical X-ray spectroscopic and diffraction characterization will be connected to ab initio molecular dynamics simulations to directly identify the extent to which detrimental degradation pathways, e.g. particle cracking, oxygen loss, and transition metal reduction, are avoided with the use of aluminum coatings. The research will provide insight into atomic level processes in order to guide the development of robust coating layers that can be scaled up into manufacturing-grade testing.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.