EFRI DCheM: Electrifying CO2 From Point Sources into Pure Liquid Fuels

EFRI DCheM：将二氧化碳从点源转化为纯液体燃料

• 批准号: 2029442
• 负责人: Haotian Wang
• 金额: $ 200万
• 依托单位: William Marsh Rice University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2020
• 资助国家: 美国
• 起止时间: 2020-09-01 至 2024-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2029442&HistoricalAwards=false
• 关键词: EFRI; DCheM; Electrifying; CO2; Point

The project supports research toward development of an electrochemical modular system to directly convert waste carbon dioxide (CO2) into pure liquid fuels. The resulting technology will provide a sustainable, negative-carbon, low-waste, and point-source manufacturing path preferable to traditional large-scale chemical process plants. This alternative and distributed route will further extend the wide range applications of liquid fuels as energy carriers and chemical feedstocks, and, more importantly, shift a significant portion of energy consumption from fossil fuels to renewable electricity while reducing carbon dioxide emissions. Beyond the direct research thrusts, the project includes broadening participation activities with the goal of increasing access to science of diverse groups, establishing a community of researchers focused on electrochemical solutions to carbon dioxide remediation, and building a competent and engaged workforce of engineers and scientists. Converting waste CO2 into valuable chemicals and fuels, with the input of renewable electricity, can distribute the way we produce chemical feedstocks, while making significant contributions to establish an anthropogenic carbon loop. Nevertheless, significant challenges still need to be overcome before this renewable route can be applied practically on a commercial scale. Typically, the electrochemical CO2 reduction reaction (CO2RR) - to generate C1 to C3 liquid fuels - involves use of solutes mixed with liquid electrolyte, which subsequently necessitates energy- and cost-intensive separation processes to recover pure liquid fuel solutions. In addition, there is still a lack of highly selective and efficient CO2RR catalysts for target products. To address these challenges, the project integrates interdisciplinary expertise including catalysts and novel electrolyzer design, polymer engineering, density functional theory simulations, and CO2 capture to build an electrochemical modular system as a platform for a continuous conversion process of simulated flue gas to pure liquid fuels. The project addresses both materials level design and device level engineering, with topics ranging from molecular scale simulation to mesoscopic mass diffusion to macroscopic system integration. Experiments and simulations are closely integrated in each component of the project, forming a systematic feedback loop to accelerate design and understanding of CO2 capture and conversion systems tailored for small-scale distributed chemical manufacturing. Beyond the immediate target of CO2 valorization, the project will establish a knowledge base and system platform for point-source manufacturing of liquid products from a range of low-value gaseous feed sources.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

该项目支持开发电化学模块化系统的研究，以直接将废二氧化碳（CO2）转化为纯液体燃料。由此产生的技术将提供一种比传统大型化工厂更好的可持续、负碳、低废物和点源制造路径。这种替代和分布式路线将进一步扩大液体燃料作为能源载体和化学原料的广泛应用，更重要的是，将大部分能源消耗从化石燃料转移到可再生电力，同时减少二氧化碳排放。除了直接的研究目标，该项目还包括扩大参与活动，以增加不同群体的科学机会，建立一个专注于二氧化碳修复电化学解决方案的研究人员社区，并建立一支有能力和敬业的工程师和科学家队伍。将废弃的二氧化碳转化为有价值的化学品和燃料，加上可再生电力的投入，可以改变我们生产化学原料的方式，同时为建立人为碳循环做出重大贡献。尽管如此，在这种可再生路线能够以商业规模实际应用之前，仍然需要克服重大挑战。通常，电化学CO2还原反应（CO2 RR）-产生C1至C3液体燃料-涉及使用与液体电解质混合的溶质，这随后需要能量和成本密集的分离过程来回收纯液体燃料溶液。此外，仍然缺乏用于目标产物的高选择性和高效的CO2 RR催化剂。为了应对这些挑战，该项目整合了跨学科的专业知识，包括催化剂和新型电解槽设计，聚合物工程，密度泛函理论模拟和CO2捕获，以构建电化学模块化系统作为模拟烟气到纯液体燃料的连续转化过程的平台。该项目涉及材料级设计和设备级工程，主题从分子尺度模拟到介观质量扩散到宏观系统集成。实验和模拟紧密结合在项目的每个组成部分中，形成了一个系统的反馈回路，以加速为小规模分布式化学制造量身定制的二氧化碳捕获和转化系统的设计和理解。除了二氧化碳价格稳定的直接目标外，该项目还将建立一个知识库和系统平台，用于从一系列低价值气体进料源生产液体产品。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Origin of Selective Production of Hydrogen Peroxide by Electrochemical Oxygen Reduction

• DOI: 10.1021/jacs.1c02186
• 发表时间: 2021-06-16
• 期刊: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
• 影响因子: 15
• 作者: Zhao, Xunhua;Liu, Yuanyue
• 通讯作者: Liu, Yuanyue

Recovering carbon losses in CO2 electrolysis using a solid electrolyte reactor

• DOI: 10.1038/s41929-022-00763-w
• 发表时间: 2022-04-18
• 期刊: NATURE CATALYSIS
• 影响因子: 37.8
• 作者: Kim, Jung Yoon 'Timothy';Zhu, Peng;Wang, Haotian
• 通讯作者: Wang, Haotian

Direct and continuous generation of pure acetic acid solutions via electrocatalytic carbon monoxide reduction

• DOI: 10.1073/pnas.2010868118
• 发表时间: 2020-12
• 期刊: Proceedings of the National Academy of Sciences
• 作者: Peng Zhu;Chuan Xia;Chun-Yen Liu;Kun Jiang;G. Gao;Xiao Zhang;Yang Xia;Yongjiu Lei;H. Alshareef;T. Senftle;Haotian Wang

High-purity and high-concentration liquid fuels through CO2 electroreduction

• DOI: 10.1038/s41929-021-00694-y
• 发表时间: 2021-11
• 期刊: Nature Catalysis
• 影响因子: 37.8
• 作者: Peng Zhu;Haotian Wang

Ultrafine Oxygen-Defective Iridium Oxide Nanoclusters for Efficient and Durable Water Oxidation at High Current Densities in Acidic Media

• DOI: 10.1039/d0ta07093a
• 发表时间: 2021-05
• 期刊: ECS Meeting Abstracts
• 作者: Lifeng Liu;Zhiyan Yu