Charge Transporting Supramolecular pi-Donor/Acceptor Arrays Based on Redox-Active Metallacycles, Metal-Organic Cages, and Daisy-Chain Coordination Polymers

在化学系大分子、超分子和纳米化学(MSN)计划的支持下，克莱姆森大学的Sourav Saha将开发电荷传导和光捕获超分子组件，该组件由限制在超分子容器中的精确组织的电子供体和受体单元组成。电子供体和受体芳香族分子包含共轭的pi-系统，当它们像一副纸牌一样表面pi堆叠时，允许电子通过共振的键和通过空间进行电子离域。此外，电活性芳香族分子经常吸收和发射光，从而显示出迷人的光学性质。当富电子(pi供体)和缺电子(pi受体)体系以交替的方式组织时，它们的电流传导能力进一步增强，这是由于电子通过电荷转移甚至部分电子转移作用从给体到受体单元的跨空间电子离域。在克莱姆森的SAHA小组进行的这项研究中，重复的电子给体和受体单元将通过将它们封装在专门设计的超分子容器中来堆叠。容器将使用铂金属离子和有机连接物建造，以精确控制其尺寸以及电子和光学性能。因此，它们将容纳不同大小的pi给体和受体单元，以调节它们的三维有序和取向。这项工作产生的结果可能会导致新类别的半导体、晶体管、光捕获系统以及电致变色和热致变色材料。萨哈博士将致力于培训和指导不同的本科生和研究生群体，通过克莱姆森的Eureka为高中高年级学生提供研究经验！该计划旨在为主要来自佐治亚州南部大学的少数族裔学生提供职业指导和动力，让他们通过“做一天的研究生”计划继续研究生教育。此外，贝克学院中学和罗珀山科学博物馆将开展本地推广计划，以吸引K-12学生并鼓励他们考虑在STEM(科学、技术、工程和数学)领域接受高等教育。这项研究将集中于利用氧化还原活性多组分金属环、金属有机笼子和菊花链配位聚合物作为超分子容器来合成、组装和结构-功能关系强大的超分子pi-供体/受体阵列，这些超分子容器可以将氧化还原互补的客体pi-系统封装在其腔内。三组分的矩形金属环和四方棱柱金属环由两个平行的氧化还原活性表面和由多个铂角连接的可变长度的正交连接体组成，将被用作超分子容器来包裹氧化还原互补的客体。容器和它们的客体包合物将被协调连接，以组装菊花链聚合物。重点将放在通过系统地改变主体的空腔大小以及主体和客体的氧化还原性质来控制离散的pi给体/受体堆栈的形成。包合物的结构和组成将使用一套结晶学、光谱和电子显微镜技术来确定。将进行系统的研究，以考察主/客体和客体/客体的电荷转移和电子转移相互作用如何影响所产生的包合物的颜色、发射、带隙和电荷传输能力。这项工作如果成功，将开发一种新的自下而上的策略，使用氧化还原活性的超分子容器组装强大的超分子pi施主/受主堆栈，并为它们在未来的电子和光伏设备中作为超分子导线、半导体和捕光材料的应用铺平道路。该奖项反映了NSF的法定使命，并通过使用基金会的智力优势和更广泛的影响审查标准进行评估，被认为值得支持。

With the support from the Macromolecular, Supramolecular, and Nanochemistry (MSN) program in the Division of Chemistry, Sourav Saha of Clemson University will be developing charge-conducting and light-harvesting supramolecular assemblies consisting of precisely organized electron donor and acceptor units confined to supramolecular containers. Electron donor and acceptor aromatic molecules contain conjugated pi-systems that allow electron delocalization through bonds via resonance as well as through space when they are cofacially pi-stacked like a deck of cards. In addition, electroactive aromatic molecules often absorb and emit light, thereby displaying fascinating optical properties. When electron rich (pi-donors) and deficient (pi-acceptor) pi-systems are organized in an alternating fashion, their ability to conduct electrical current is further accentuated due to facile through-space electron delocalization from the donor to the acceptor units via charge-transfer and even partial electron transfer interactions. In this research conducted by the Saha group at Clemson, repeating electron donor and acceptor units will be stacked by encapsulating them within specifically designed supramolecular containers. The containers will be constructed using platinum metal ions and organic linkers to precisely control their dimensions and electronic and optical properties. As such, they will accommodate pi-donor and acceptor units of different sizes to regulate their three-dimensional ordering and orientation. The results generated by this work can potentially to lead to new class of semiconductors, transistors, light-harvesting systems, and electrochromic and thermochromic materials. Dr. Saha will work to train and mentor diverse groups of undergraduate and graduate students, provide research experience to high school seniors through Clemson’s EUREKA! program, and offer career guidance and motivation to largely minority students from Georgia Southern University to pursue graduate education through a ‘Be a Grad Student for a Day’ initiative. In addition, local outreach programs at Beck Academy Middle School and Roper Mountain Science Museum will be conducted to engage K-12 students and encourage them to consider pursuing higher education in STEM (science, technology, engineering and mathematics) fields.This research will focus on the synthesis, assembly, and structure–function relationship studies of robust supramolecular pi-donor/acceptors arrays using redox-active multicomponent metallacycles, metal-organic cages, and daisy chain coordination polymers as supramolecular containers that can encapsulate redox-complementary guest pi-systems inside their cavities. Tricomponent rectangular metallacycles and tetragonal prismatic metallacages consisting of two parallel redox-active faces and orthogonal linkers with variable lengths connected by heteroligated platinum corners will be employed as supramolecular containers to encapsulate redox-complementary guests. The containers and their guest-inclusion complexes will be coordinatively linked to assemble daisy-chain polymers. Emphasis will be placed on controlling the formation of discrete pi-donor/acceptor stacks through systematic variations of the cavity size of the hosts and the redox properties of the hosts and guests. The structures and compositions of inclusion complexes will be determined using a suite of crystallographic, spectroscopic, and electron microscopic techniques. Systematic studies will be conducted to examine how the host/guest and guest/guest charge-transfer and electron-transfer interactions will influence the color, emission, bandgaps, and charge transport capability of the resulting inclusion complexes. This work, if successful, will develop a novel bottom-up strategy to assemble robust supramolecular pi-donor/acceptor stacks using redox-active supramolecular containers and pave way to their applications as supramolecular wires, semiconductors, and light-harvesting materials in future electronic and photovoltaic devices.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.