Renewal: Overcoming Energy Loss in Organic Bulk Heterojunctions

更新：克服有机体异质结的能量损失

• 批准号: 2212146
• 负责人: Stephen Forrest
• 金额: $ 66.66万
• 依托单位: Regents of the University of Michigan - Ann Arbor
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2022
• 资助国家: 美国
• 起止时间: 2022-07-01 至 2025-06-30
• 项目状态: 未结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2212146&HistoricalAwards=false
• 关键词: Renewal; Overcoming; Energy; Loss; Organic

Non-technical Description. Solar technologies are increasingly providing energy across the US at costs well below even that of fossil fuels. In short, solar energy is delivering on its promise as a source of low cost, clean and renewable energy. However, solar solutions have largely been based on silicon, which is far from an optimal solution. New solutions must have the objective of making solar power ubiquitous, helping to fulfill our ever-expanding energy needs. These include solar power generating windows and building-integrated photovoltaics as well as devices that operate at very low light levels to scavenge waste illumination power. This is an urgent and fundamental technological challenge. Recently, there have been dramatic increases in the efficiency of potentially low-cost organic solar cells to over 19%, approaching that of silicon cells. This project is directed at determining the ultimate power conversion efficiency of organic solar cells. The investigators will study new organic materials with state-of-the-art optical spectroscopy to understand the power generating mechanisms that limit the efficiency of organic solar cells. The principles derived from these studies can provide molecular design rules and guide the improvement of organic solar cells towards their theoretical limit of ~25% efficiency. The project supports training of a diverse workforce through the education of graduate and undergraduate students in materials design, synthesis, and characterization, coupled with device engineering and scientific communication. The PIs will recruit and retain a diverse next generation of students in STEM fields through diversity, equity and inclusion efforts at the University of Michigan, including outreach to underrepresented groups and hosting a Conference for Undergraduate Women in Physics.Technical Description. The primary goal of this project is to understand and improve organic photovoltaic (OPV) devices through improved materials and device design strategies based on quantum mechanical models. Dramatically reduced energy losses in the charge photogeneration process may ultimately provide a pathway towards ultralow cost solar power in situations where established, mature solar technologies are less effective. Beyond solar energy harvesting, these systems open new avenues for engineering materials for charge and energy transport at the atomistic level, and for their exploitation in applications as light emission, energy and charge transfer over exceptional distances, and may even result in extending electronic technology well beyond its current limits. This project combines the investigators’ extensive expertise in OPV materials, design and characterization with state-of-the-art and emerging multidimensional spectroscopies to understand the energy loss mechanisms that currently limit single junction organic solar cell device efficiencies. The principles derived from these fundamental studies provide molecular design rules to guide the improvement of cell efficiencies towards their thermodynamic limit of ~25%. The work significantly expands the spectroscopic toolbox for probing OPVs, providing transformative opportunities for understanding the mechanisms of charge generation and concomitant energy losses. The research has the following primary goals: (i) Gain a fundamental understanding of the mechanisms governing charge generation and energy loss at organic heterojunctions (HJs) to increase the solar-to-electrical power conversion efficiency to near the thermodynamic limit; (ii) Map the complete HJ charge photogeneration process using multidimensional spectroscopy to probe the mechanisms of charge generation and the origins of energy loss; (iii) Exploit ultrastrong coupling in unique light harvesting architectures to realize exciton-polariton transfer with near-zero energy loss.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术描述。太阳能技术越来越多地为美国各地提供能源，其成本甚至远低于化石燃料。简而言之，太阳能正在兑现其作为低成本、清洁和可再生能源的承诺。然而，太阳能解决方案在很大程度上是基于硅的，这远非最佳解决方案。新的解决方案必须以使太阳能无处不在为目标，帮助满足我们不断扩大的能源需求。这些包括太阳能发电窗口和建筑集成光伏发电，以及在非常低的光水平下运行的设备，以清除废弃的照明功率。这是一项紧迫而根本性的技术挑战。最近，潜在的低成本有机太阳能电池的效率已经大幅提高到19%以上，接近硅电池的效率。该项目旨在确定有机太阳能电池的最终功率转换效率。研究人员将用最先进的光谱学研究新的有机材料，以了解限制有机太阳能电池效率的发电机制。从这些研究中得出的原理可以提供分子设计规则，并指导有机太阳能电池朝着其理论极限~25%效率的方向改进。该项目通过对研究生和本科生进行材料设计、合成和表征方面的教育，以及设备工程和科学交流，支持培养多样化的劳动力。这些pi将通过密歇根大学的多元化、公平和包容努力，在STEM领域招募和留住多元化的下一代学生，包括向代表性不足的群体推广，并举办物理学本科女性会议。技术描述。该项目的主要目标是通过改进基于量子力学模型的材料和器件设计策略来理解和改进有机光伏（OPV）器件。在现有的成熟太阳能技术效率较低的情况下，在电荷光发电过程中大幅减少能量损失可能最终为超低成本太阳能发电提供途径。除了太阳能收集之外，这些系统还为原子水平上的电荷和能量传输的工程材料开辟了新的途径，并为它们在光发射、超距离能量和电荷传输方面的应用开发开辟了新的途径，甚至可能导致电子技术的扩展远远超出其当前的极限。该项目将研究人员在OPV材料、设计和表征方面的广泛专业知识与最先进和新兴的多维光谱相结合，以了解目前限制单结有机太阳能电池设备效率的能量损失机制。从这些基础研究中得出的原理提供了分子设计规则，以指导电池效率的提高，使其达到25%的热力学极限。这项工作极大地扩展了探测opv的光谱工具箱，为理解电荷产生机制和伴随的能量损失提供了革命性的机会。本研究的主要目标是：(1)获得对有机异质结（HJs）电荷产生和能量损失机制的基本理解，以提高太阳能到电力的转换效率，使其接近热力学极限；（ii）利用多维光谱绘制HJ电荷光产生的完整过程，探索电荷产生的机制和能量损失的来源；（iii）利用独特的光收集结构中的超强耦合，实现能量损失接近于零的激子-极化子转移。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。