CAS: Bidirectional Molecular Catalysts to Control Dinitrogen Reduction and Ammonia Oxidation

CAS：控制氮还原和氨氧化的双向分子催化剂

• 批准号: 2247748
• 负责人: Michael Mock
• 金额: $ 54.58万
• 依托单位: Montana State University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2023
• 资助国家: 美国
• 起止时间: 2023-07-01 至 2026-06-30
• 项目状态: 未结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2247748&HistoricalAwards=false
• 关键词: CAS; Bidirectional; Molecular; Catalysts; Control

With the support of the Chemical Catalysis program in the Division of Chemistry, Michael Mock of Montana State University is studying ways to store energy by developing metal catalysts to convert dinitrogen gas found in air to a fuel such as ammonia. Understanding the transformation between nitrogen and ammonia offers a potential carbon-free fuel cycle to interconvert chemical and electrical energy. The project will focus on the synthesis of new catalysts using inexpensive metals such as chromium, iron, and nickel. By design, the novel behavior of these catalysts will be used to both form ammonia and convert ammonia to nitrogen. The project will establish strategies for the interconversion of nitrogen and ammonia by removing and attaching hydrogen atoms using chemical reagents, electricity, and/or light energy in conjunction with the metal catalysts. Additionally, the Mock group will host Native American undergraduate students from Montana Tribal Colleges to work in the laboratory to learn about synthetic chemistry and catalysis, and to acquire hands-on laboratory skills. Providing hands-on experience in chemistry to Native American students will serve to increase the involvement of underrepresented minorities in chemistry and will contribute to strengthening the technical workforce in Montana and in the United States. This project will enable outreach activities at area primary and secondary schools to engage students on the topics of renewable forms of energy and new energy technologies. Science outreach activities at area schools will engage students on the topics of renewable forms of energy and new energy technologies that have a positive impact on the environment and society. Under this project, Professor Michael Mock of Montana State University is studying molecular catalytic systems to develop a nitrogen-based cycle to store and utilize energy in N–H bonds. Catalysts using chromium and iron will be designed for the interconversion of dinitrogen (N2) and ammonia (NH3). The project will likely lead to a better mechanistic understanding of H-atom transfer reactions of the same catalyst for both N2 reduction and NH3 oxidation. hence assessing the concept of microscopic reversibility for two challenging multi-proton, multi-electron reactions involving making and breaking N–N and N–H bonds. A common strategy of delivery of H-atoms to N2 and the removal of H-atoms from NH3 ligands will be accomplished by using chemical reagents, electrocatalytic conditions, and/or light energy. The project will measure thermodynamic N–H bond strengths and characterize metal-NxHy intermediates to advance catalyst design. The proposed work will use Ni-based platforms for understanding homolytic N–H bond cleavage and N–N coupling steps en route to dinitrogen formation.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

在化学系化学催化项目的支持下，蒙大拿州立大学的迈克尔·莫克正在研究通过开发金属催化剂将空气中的二氮气体转化为氨等燃料来储存能量的方法。了解氮和氨之间的转化提供了一个潜在的无碳燃料循环，以相互转换化学能和电能。该项目将重点关注使用廉价金属（如铬、铁和镍）合成新催化剂。通过设计，这些催化剂的新特性将用于形成氨和将氨转化为氮。该项目将制定氮和氨相互转化的策略，通过使用化学试剂，电力和/或光能与金属催化剂结合来去除和附着氢原子。此外，模拟组将接待来自蒙大拿部落学院的美洲原住民本科生在实验室工作，学习合成化学和催化，并获得动手实验室技能。向美洲原住民学生提供化学方面的实践经验，将有助于增加代表性不足的少数群体对化学的参与，并将有助于加强蒙大拿州和美国的技术劳动力。该项目将使该地区的中小学能够开展外联活动，让学生参与可再生能源和新能源技术的专题。 地区学校的科学推广活动将使学生参与对环境和社会产生积极影响的可再生能源形式和新能源技术的专题。 在该项目下，蒙大拿州立大学的Michael Mock教授正在研究分子催化系统，以开发一种基于氮的循环，以储存和利用N-H键中的能量。使用铬和铁的催化剂将被设计用于二氮（N2）和氨（NH3）的相互转化。该项目可能会导致更好地理解氢原子转移反应的相同催化剂的N2还原和NH3氧化。 因此，评估微观可逆性的概念，两个具有挑战性的多质子，多电子反应，涉及制造和打破N-N和N-H键。将H-原子递送到N2和从NH3配体去除H-原子的常见策略将通过使用化学试剂、电催化条件和/或光能来实现。该项目将测量热力学N-H键强度并表征金属-NxHy中间体，以推进催化剂设计。这项工作将使用镍基平台来理解均裂N-H键断裂和N-N偶联步骤，从而形成二氮。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。