Mechanisms of organic reactions in complex environments and confined volumes elucidated by laser desorption mass and ion mobility spectrometry

通过激光解吸质量和离子迁移谱阐明复杂环境和有限体积中的有机反应机制

• 批准号: 275653032
• 负责人: Professor Dr. Bernd Abel
• 金额: --
• 依托单位: Institut für Technische Chemie
• 依托单位国家: 德国
• 项目类别: Research Units
• 财政年份: 2015
• 资助国家: 德国
• 起止时间: 2014-12-31 至 2022-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/275653032?language=en
• 关键词: Mechanisms; organic; reactions; complex; environments

The aim of the project is to measure complex reactions online and to analyze the results with quantum theory in order to unravel the underlying mechanisms. A special focus of the project is organic reactions in microdroplets and thin films and we aim at an in depth investigation of reaction acceleration in confined volumes, that has been recently discovered. We employ IR desorption mass and ion mobility spectrometry and various microjet and microdroplet technologies in combination with quantum theory. These unique tools will enable us to investigate complex reactions and reaction rate acceleration factors in confined volumes, i.e. aqueous or non-aqueous micron sized droplets and thin films.

该项目的目的是在线测量复杂的反应，并用量子理论分析结果，以揭示潜在的机制。该项目的一个特别重点是微滴和薄膜中的有机反应，我们的目标是深入研究最近发现的封闭体积中的反应加速。我们采用红外解吸质谱和离子迁移谱和各种微射流和微滴技术结合量子理论。这些独特的工具将使我们能够研究复杂的反应和反应速率加速因素在有限的体积，即水或非水微米大小的液滴和薄膜。