Synthesis of Covalently Linked Organic Frameworks via Reversible Nitroxide-Exchange Reaction (C05)

这个项目的目的是合成分子精确的聚合物网络。我们的方法是基于氮氧化物交换反应（NER）来结合多主题分子组分。NER的可逆和动态特性允许在合成过程中进行自组装和纠错，并且还提供了通过氮氧化物介导聚合（NMP）将单体纳入网络的可能性。在一种先进的方法中，我们将实现敏化烷氧胺，在网络中产生光动力共价键。这种方法将允许我们改变网络的反应平衡，从溶液到固态，使用光和温度作为触发器。

The aim of this project is to synthesise molecularly precise polymer networks. Our approach is based on the nitroxide exchange reaction (NER) to combine multitopic molecular components. The reversible and dynamic nature of NER allows self-assembly and error correction during synthesis, and additionally offers the possibility to include monomers within the networks via nitroxide mediated polymerisation (NMP). In an advanced approach we will implement sensitised alkoxyamines, generating photodynamic covalent bonds in the networks. This approach will allow us to shift the reaction equilibrium of the networks, form solution to solid state, using light and temperature as triggers.