Chiral Functionalised Ionic Liquids as Reaction Media

Chiril Fun项目致力于新型手性功能化离子液体的开发，旨在从分子和物理化学水平上全面了解催化体系的控制机制。溶解的有机化合物与离子液体之间的相互作用是手性从手性溶剂转移到底物上的关键。通过使用有机催化、过渡金属催化和纳米催化作为分子探针，将实现对这些相互作用的表征和量化。核磁共振和红外光谱测量的结果将支持对底物和离子液体之间相互作用的量化。从长远来看，这些基础研究将有助于合理地研究手性离子液体介质中的不对称催化。

The project ChirIL Fun is concerned with the development of novel chiral functionalised ionic liquids and aims at a general understanding of the control mechanism in catalytic systems on a molecular and physico-chemical level. Interactions between dissolved organic compounds and the ionic liquid are essential for a chirality transfer from the chiral solvent onto the substrate. A characterisation and quantification of these interactions will be achieved by the use of organocatalysis, transition metal catalysis and nanocatalysis as molecular probes. A quantification of the interactions between the substrate and the ionic liquid will be supported by the results from NMR and IR spectroscopic measurements. In the long term, these fundamental studies will contribute to a rational approach to asymmetric catalysis in chiral ionic liquid media.