Porous porphyrin solids for photochemical applications

制备了基于氧化卟啉的化合物，并测试了它们对单线态氧的光化学产生的作用。然后将其用于有机基质的氧化和作为抗菌材料的测试。制备了锆基多孔配位聚合物，发现其具有良好的单线态氧生成效率。然后，这些材料用于氧化小的有机分子，作为药物中间体或有毒材料的模型。本工作已发表，制备了另一类多孔聚合物，发现这些材料对模型底物的氧化具有更好的选择性。还测试了其他大环的单线态氧生成。

Compounds based on oxidized porphyrins were prepared and tested for their action for the photochemical generation of singlet oxygen. The materials were then utilized for oxidation of organic substrate and tested for use as antimicrobial materials.The zirconium-based porous coordination polymers were prepared and were found to generate singlet oxygen with good efficiency. These materials were then used to oxidize small organic molecules as models for pharmaceutical intermediates or toxic materials. This work was published.Another class of porous polymers was prepared and those materials were found to promote oxidation of the model substrate with better selectivity for mild oixidation. Other macrocycles were also tested for singlet oxygen generation.