Porous porphyrin solids for photochemical applications

制备了以氧化卟啉为基础的化合物，并对其光化学生成单线态氧的作用进行了测试。然后将这些材料用于有机底物的氧化并测试用作抗菌材料。制备了锆基多孔配位聚合物，并发现其生成单线态氧的效率较高。然后这些材料被用来氧化小有机分子作为药物中间体或有毒物质的模型。这篇文章发表了。制备了另一类多孔聚合物，发现这些材料促进了模型底物的氧化，对轻度氧化有更好的选择性。其他大循环也测试了单线态氧生成。

Compounds based on oxidized porphyrins were prepared and tested for their action for the photochemical generation of singlet oxygen. The materials were then utilized for oxidation of organic substrate and tested for use as antimicrobial materials.The zirconium-based porous coordination polymers were prepared and were found to generate singlet oxygen with good efficiency. These materials were then used to oxidize small organic molecules as models for pharmaceutical intermediates or toxic materials. This work was published.Another class of porous polymers was prepared and those materials were found to promote oxidation of the model substrate with better selectivity for mild oixidation. Other macrocycles were also tested for singlet oxygen generation.