Chiral porphyrin complexes for sensing and asymmetric catalysis

用于传感和不对称催化的手性卟啉配合物

• 批准号: 17F17825
• 负责人: HILL Jonathan
• 金额: $ 1.41万
• 依托单位: National Institute for Materials Science
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for JSPS Fellows
• 财政年份: 2017
• 资助国家: 日本
• 起止时间: 2017-11-10 至 2020-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17F17825/
• 关键词: Porphyrin; Chirality; Dimer; Macrocycle; Self-assembly

Synthesis of chiral binaphthyl porphyrin dimers for guest binding was completed and the work has been published. The compounds were found to be multichannel sensors for enantiomeric excess of chiral compounds. Related work on resorcinarene macrocycles has been completed and published. Those compounds were found useful for sensing acidity and for generation of singlet oxygen. Further allied work on the novel catalytic properties of the compounds has been completed and published.Other work is ongoing in collaboration with Dr. Payne.

合成了用于客体结合的手性联萘卟啉二聚体，并发表了论文。这些化合物被发现是手性化合物的对映体过量的多通道传感器。间苯二酚芳烃大环化合物的相关工作已经完成并发表。发现这些化合物可用于感测酸度和产生单线态氧。关于这些化合物的新催化性质的进一步相关工作已经完成并发表。其他工作正在与佩恩博士合作进行。

项目成果

Non-Planar beta-Substituted Porphyrinoids as Hydrogen-Bond Donor Catalysts

非平面β-取代卟啉作为氢键供体催化剂

• 发表时间: 2019
• 作者: Daniel T. Payne;Whitney A. Webre;Yoshitaka Matsushita;Nianyong Zhu;Zdenek Futera;Jan Labuta;Wipakorn Jevasuwan;Naoki Fukata;John S. Fossey;Francis D’Souza;Katsuhiko Ariga;Wolfgang Schmitt;Jonathan P. Hill;Daniel T. Payne;Daniel T. Payne
• 通讯作者: Daniel T. Payne

Resorcinarenes as Molecular Switches

间苯二芳烃作为分子开关

• 发表时间: 2019
• 作者: Daniel T. Payne;Whitney A. Webre;Yoshitaka Matsushita;Nianyong Zhu;Zdenek Futera;Jan Labuta;Wipakorn Jevasuwan;Naoki Fukata;John S. Fossey;Francis D’Souza;Katsuhiko Ariga;Wolfgang Schmitt;Jonathan P. Hill;Daniel T. Payne
• 通讯作者: Daniel T. Payne

Knock-on synthesis of tritopic calix[4]pyrrole host for enhanced anion interactions

• DOI: 10.1039/c9dt02365h
• 发表时间: 2019-11-07
• 期刊: DALTON TRANSACTIONS
• 影响因子: 4
• 作者: Chahal, Mandeep K.;Labuta, Jan;Hill, Jonathan P.
• 通讯作者: Hill, Jonathan P.

Diporphyrin tweezer for multichannel spectroscopic analysis of enantiomeric excess

• DOI: 10.1007/s11705-019-1869-1
• 发表时间: 2020-01
• 期刊: Frontiers of Chemical Science and Engineering
• 影响因子: 4.5
• 作者: D. Payne;M. Chahal;Václav Březina;Whitney A Webre;K. Ariga;F. D’Souza;J. Labuta;Jonathan P. Hill

Oxidation-Induced Isomerisation and hemiquinhydrone complex formation of an Anti-Oxidant-Substituted Resorcinarenes

抗氧化剂取代间苯二芳烃的氧化诱导异构化和半醌氢酮络合物形成

• 发表时间: 2019
• 作者: Daniel T. Payne;Whitney A. Webre;Yoshitaka Matsushita;Nianyong Zhu;Zdenek Futera;Jan Labuta;Wipakorn Jevasuwan;Naoki Fukata;John S. Fossey;Francis D’Souza;Katsuhiko Ariga;Wolfgang Schmitt;Jonathan P. Hill;Daniel T. Payne;Daniel T. Payne;Daniel T. Payne
• 通讯作者: Daniel T. Payne