ＮＭＲ検出のためペリレンジイミド由来の薬剤を素にした新たなディスコティック液晶

完成了几类手性苝酰亚胺（高着色颜料）的合成和纯化，包括非离子和阳离子化合物。研究了化合物的物理性质，揭示了它们在溶液中组装成手性结构，并在水溶剂混合物中形成手性液晶。考察了溶剂和浓度的影响。将该液晶化合物用于NMR实验，以测定对映体过量。这些材料的手性自组装被金属化，形成适合于可能的催化应用的手性配位络合物。

Synthesis and purification of several classes of chiral perylene diimide (highly colored pigments) including amionic and cationic compounds was completed. Physical properties of the compounds were investigated revealing their assembly into chiral structures in solutions and formation of cholesteric liquid crystals in aqueous solvent mixtures. The effects of solvent and concentration were investigated. The liquid crystal compounds were applied in NMR experiments for the determination of enantiomeric excess. Chiral self-assemblies of the materials were metallated forming chiral coordination complexes suitable for possible catalytic applications.Two manuscripts in preparation.