Development of New Organic Metals Based on TTF Derivatives

基于TTF衍生物的新型有机金属的开发

• 批准号: 06640752
• 负责人: YAMADA Jun-ichi
• 金额: $ 1.34万
• 依托单位: Himeji Institute of Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for General Scientific Research (C)
• 财政年份: 1994
• 资助国家: 日本
• 起止时间: 1994 至 1995
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-06640752/
• 关键词: Tetrathiafulvalene; Organotin compounds; Lewis acid; Electrophiles; DHTTF derivative; DSDTF derivative; TTFs-fused donors; BEDT-TTF derivative; TTF有機合成金属; 対称TTF誘導体; 非対称TTF誘導体; ノン-カップリング反応; 結晶育成; 制御電流法; 単結晶; 電荷移動錯体

The efficient syntheses of unsymmetrical tetrathiafulvalenes (TTFs), as well as symmetrical TTFs, were accomplished by the Lewis acid-mediated reactions of organotin compounds with electrophiles. The synthesis of unsymmetrical TTFs could be carried out by the Me_3Al-promoted noncoupling reactions without tedious separation procedure. In addition, this synthetic method could also be applicable to the preparation of TTFs-fused donors. Moreover, BEDT-TTF derivatives condensed with heterocycles could be synthesized systematically via the BF_3-promoted reaction. We have accomplished the development of new organic metals based on (1) the DHTTF (dihydrotetrathiafulvalene) derivative, (2) the DSDTF (diselenadithiafulvalene) derivative, (3) TTFs-fused donors, and (4) the BEDT-TTF derivative fused with 1,4-dioxane ring.

利用有机锡化合物与亲电试剂的刘易斯酸反应，高效合成了不对称四硫富瓦烯（TTFs）和对称TTFs。不对称TTFs的合成可通过Me 3Al促进的非偶联反应进行，无需繁琐的分离步骤。此外，该合成方法也适用于TTFs融合供体的制备。此外，在BF_3的催化下，还可以系统地合成BEDT-TTF衍生物。我们已经完成了基于（1）DHTTF（二氢四硫富瓦烯）衍生物、（2）DSDTF（二硒二硫富瓦烯）衍生物、（3）TTFs-稠合给体和（4）与1，4-二氧六环稠合的BEDT-TTF衍生物的新有机金属的开发。

项目成果

H.Anzai: "Crystal Growth of Organic Charge-transfer Complex by Electrocrystallization with Controlled Applied Current" J.Crystal Growth. 154. 145-150 (1995)

H.Anzai：“通过受控应用电流的电结晶实现有机电荷转移复合物的晶体生长”J.Crystal Growth。

H. Anzai: "Crystal Growth of Organic Charge‐transfer Complex by Electrocrystallization with Controlled Applied Current" J. Crystal Growth. 154. 145-150 (1995)

H. Anzai：“通过受控电流的电结晶实现有机电荷转移复合物的晶体生长”J. Crystal Growth 154. 145-150 (1995)

J.Yamada et al.: "Noncoupling Synthesis of Unsymmetrical Tetrathia-fulvalene Derivatives.Dihydrotetrathiafulvalenes...." Journal of the American Chemical Society. 117. 1149-1150 (1995)

J.Yamada 等人：“不对称四硫富瓦烯衍生物的非偶联合成。二氢四硫富瓦烯......”美国化学会杂志。

J. Yamada: "Noncoupling Synthesis of Unsymmetrical Tetrathiafulvalene Derivatives.Dihydrotetrathiafulvalenes as New Electron Donors" J. Am. Chem. Soc.117. 1149-1150 (1995)

J. Yamada：“不对称四硫富瓦烯衍生物的非偶联合成。二氢四硫富瓦烯作为新电子供体”J. Am。

H. Anzai: "Crystal Growth of Organic Charge‐transfer Complex by Electrocrystallization with Regulated Applied Current" Synth. Met.70. 1115-1116 (1995)

H. Anzai：“通过调节电流进行有机电荷转移复合物的晶体生长”Met.70（1995）。