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Development of New Organic Metals Based on TTF Derivatives

Development of New Organic Metals Based on TTF Derivatives
基于TTF衍生物的新型有机金属的开发
批准号：
06640752
负责人：
YAMADA Jun-ichi
金额：
$1.34万
依托单位：
Himeji Institute of Technology
依托单位国家：
日本
项目类别：
Grant-in-Aid for General Scientific Research (C)
财政年份：
1994
资助国家：
日本
项目状态：
已结题
起止时间：
1994 至 1995
来源：
https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-06640752/
关键词：
TetrathiafulvaleneOrganotin compoundsLewis acidElectrophilesDHTTF derivativeDSDTF derivativeTTFs-fused donorsBEDT-TTF derivativeTTF有機合成金属対称TTF誘導体非対称TTF誘導体ノン-カップリング反応結晶育成制御電流法単結晶電荷移動錯体

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中文摘要
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英文摘要
The efficient syntheses of unsymmetrical tetrathiafulvalenes (TTFs), as well as symmetrical TTFs, were accomplished by the Lewis acid-mediated reactions of organotin compounds with electrophiles. The synthesis of unsymmetrical TTFs could be carried out by the Me_3Al-promoted noncoupling reactions without tedious separation procedure. In addition, this synthetic method could also be applicable to the preparation of TTFs-fused donors. Moreover, BEDT-TTF derivatives condensed with heterocycles could be synthesized systematically via the BF_3-promoted reaction. We have accomplished the development of new organic metals based on (1) the DHTTF (dihydrotetrathiafulvalene) derivative, (2) the DSDTF (diselenadithiafulvalene) derivative, (3) TTFs-fused donors, and (4) the BEDT-TTF derivative fused with 1,4-dioxane ring.
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H.Anzai: "Crystal Growth of Organic Charge-transfer Complex by Electrocrystallization with Controlled Applied Current" J.Crystal Growth. 154. 145-150 (1995)
H.Anzai：“通过受控应用电流的电结晶实现有机电荷转移复合物的晶体生长”J.Crystal Growth。
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通讯作者：
H. Anzai: "Crystal Growth of Organic Charge‐transfer Complex by Electrocrystallization with Controlled Applied Current" J. Crystal Growth. 154. 145-150 (1995)
H. Anzai：“通过受控电流的电结晶实现有机电荷转移复合物的晶体生长”J. Crystal Growth 154. 145-150 (1995)
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通讯作者：
J.Yamada et al.: "Noncoupling Synthesis of Unsymmetrical Tetrathia-fulvalene Derivatives.Dihydrotetrathiafulvalenes...." Journal of the American Chemical Society. 117. 1149-1150 (1995)
J.Yamada 等人：“不对称四硫富瓦烯衍生物的非偶联合成。二氢四硫富瓦烯......”美国化学会杂志。
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通讯作者：
J. Yamada: "Noncoupling Synthesis of Unsymmetrical Tetrathiafulvalene Derivatives.Dihydrotetrathiafulvalenes as New Electron Donors" J. Am. Chem. Soc.117. 1149-1150 (1995)
J. Yamada：“不对称四硫富瓦烯衍生物的非偶联合成。二氢四硫富瓦烯作为新电子供体”J. Am。
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共 11 条
    Development of Organic Superconductors by Reduction of Intermolecular Interaction
    Clarification and Application of the Steric Factors in Organic Conductors
    • 批准号：
      10640565
    • 项目类别：
      Grant-in-Aid for Scientific Research (C)
    • 资助金额：
      $2.05万
    • 财政年份：
      1998
    • 负责人：
      YAMADA Jun-ichi
    • 依托单位：
      Himeji Institute of Technology
    Development of New Organic Metals Based on TTF-Fused Donor Systems via "Complexation" of Organotin Compounds
    • 批准号：
      08640694
    • 项目类别：
      Grant-in-Aid for Scientific Research (C)
    • 资助金额：
      $1.47万
    • 财政年份：
      1996
    • 负责人：
      YAMADA Jun-ichi
    • 依托单位：
      Himeji Institute of Technology
    海外基金